Abstract Treatment of [Co 2 (CO) 8 ] with the ipso -substituted P(C-X)P Y ligands (X = Br, Cl; R i Pr, t Bu) bearing NH and CH linkers under solvothermal conditions affords five-coordinate Co(I) Co(III) complexes I (PCP -R)(CO) III -R)X ]. The later are paramagnetic exhibiting a solution magnetic moment in range 3.0–3.3 μ B which is consistent d 6 intermediate spin system corresponding to two u...

A topological insulator is a new phase of quantum matter with a bulk band gap and spin-polarized surface states, which might find use in applications ranging from electronics to energy conversion. Despite much exciting progress in the field, high-yield solution synthesis has not been widely used for the study of topological insulator behavior. Here, we demonstrate that solvothermally synthesize...

A protocol for the synthesis of α-alkynylnitrones from 1,3-enynes has been developed. The process is triggered by hydromagnesiation with magnesium hydride (MgH2), which prepared in situ through solvothermal treatment iodide (MgI2) sodium (NaH) tetrahydrofuran. Downstream functionalization resulting propargylmagnesium intermediates organo nitro compounds affords α-alkynylnitrones, could be used ...

Chemically derived nanowire materials have attracted much attention because of their interesting geometries, properties, and potential applications.[1±3] Various methods have been developed for synthesizing semiconducting nanowires including laser ablation,[2,3] physical vapor deposition under high temperatures,[3±7] and solvothermal growth under high pressures and moderate temperatures.[3,8±10...

development of an eco-friendly, low cost and high energy density limnpo4 cathode material has attracted much attention due to its high operating voltage vs. li falling within the electrochemical stability window of conventional electrolyte solutions and offers more safety features due to the presence of a strong p-o covalent bond.synthesis of battery materials integrates the battery technology ...

With the current increase of interest in amorphous MOFs and ZIFs for various applications, there is a need optimal environmentally friendly synthesis parent materials. One that has received most research to date, along with ZIF-62, ZIF-76. ZIF-62 already been produced mechanochemically, while majority ZIF-76 currently using solvothermal an autoclave DMF as solvent. Herein, we present two new gr...