Geochemically diverse basalts occur in an ~160-km-wide transect that stretches across the Quaternary southern Washington Cascades (SWC) volcanic arc. Two fundamental groups of SWC basalts can be identified on the basis of major and trace element chemistry. On primitive mantle-normalized “spidergrams”, Group I lavas resemble within-plate basalts, whereas Group II lavas exhibit chemical character...

The morphology, structure, and magnetic properties of nickel ferrite (NiFe2O4) films fabricated by radio frequency magnetron sputtering on Si(111) substrate have been investigated as functions of film thickness. Prepared films that have not undergone post-annealing show the better spinel crystal structure with increasing growth time. Meanwhile, the size of grain also increases, which induces th...

Anisotropic nano-plate structures in self-assembled perovskite-spinel thin films, BiFeO3-NiFe2O4 and BiFeO3-CoFe2O4, which were deposited on (001)c SrRuO3/SrTiO3 and DyScO3 substrates, respectively, have been demonstrated using transmission electron microscopy combined with strain analysis. Unlike the unitary cube-on-cube orientation relationship reported widely, the growth direction of the CoF...

A high-pressure polymorph of chromite, the first natural sample with the calcium ferrite structure, has been discovered in the shock veins of the Suizhou meteorite. Synchrotron x-ray diffraction analyses reveal an orthorhombic CaFe2O4-type (CF) structure. The unit-cell parameters are a = 8.954(7) A, b = 2.986(2) A, c = 9.891(7) A, V = 264.5(4) A3 (Z = 4) with space group Pnma. The new phase has...

Low-temperature structures of the lithium manganese spinels were determined using TOF neutron Rietveld analysis. The spinels LiMn2O4 with different values, (0.016, 0.040, and 0.132) showed the cubic-orthorhombic phase transitions, and the lattice distortion decreased with decreasing . Although no anomaly corresponding to the cubic-orthorhombic phase transition was observed in the DSC curve for ...

Single crystalline cubic spinel LiMn2O4 nanowires were synthesized by hydrothermal method and the precursor calcinations. The phase structures and morphologies were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and high-resolution transmission electronmicroscopy (HRTEM). Galvanostatic charging/discharging cycles of as-prepared LiMn2O4 nanowires w...

Studies have been made on muscovite single crystals treated under dry and hydrothermal conditions at temperatures above 800~ The course of reaction is markedly affected by the amount of water present in the system. In the presence of a large excess of water, appreciable reaction commences at 8(~0~ with the formation of kalsilite and corundum. The kalsilite may bear an epitaxial relationship to ...

A systematic study of nine binary and ternary spinel oxides formed from Co, Al, and Fe is presented by means of density functional theory. Analysis of the structural, magnetic, and electronic properties through the series of materials is carried out. Preference for the octahedral spinel sites are found in the order Fe Co Al. The electronic band gaps of Co3O4 and Fe3O4 are shown to remain largel...