The existing thermodynamics of the cosmological horizon in de Sitter spacetime is established in the micro-canonical ensemble, while thermodynamics of black hole horizons are established in the canonical ensemble. Generally in the ordinary thermodynamics and statistical mechanics, both of the micro-canonical and canonical ensembles yield the same equation of state for any thermodynamic system. ...

The existing thermodynamics of the cosmological horizon in de Sitter spacetime is established in the micro-canonical ensemble, while the thermodynamics of black hole horizons is established in the canonical ensemble. Generally in the ordinary thermodynamics and statistical mechanics, both of the micro-canonical and canonical ensembles yield the same equation of state for any thermodynamic syste...

The laws of thermodynamics were formulated long before we knew the existence of atoms and molecules. The formal thermodynamics curriculum based on the empirical laws have been replaced by courses based on physical and statistical foundation of the subject in the intermediate courses in undergraduate curriculum for some time now. In these courses they show how the properties of macroscopic syste...

We describe recent progress towards deriving the Fundamental Laws of thermodynamics (the 0, 1, and 2 Law) from nonequilibrium quantum statistical mechanics in simple, yet physically relevant models. Along the way, we clarify some basic thermodynamic notions and discuss various reversible and irreversible thermodynamic processes from the point of view of quantum statistical mechanics.

The Bures geometry of quantum statistical thermodynamics at thermal equilibrium is investigated by introducing the connections between the Bures angle and the Rényi 1/2-divergence. Fundamental relations concerning free energy, moments of work, and distance are established.

For studying the thermodynamic properties of systems using statistical mechanics we propose an ensemble that lies in between the familiar canonical and microcanonical ensembles. From a comparative study of these ensembles we conclude that all these ensembles may not yield the same results even in the thermodynamic limit except at high temperatures. An investigation of the coupling between syste...

the present study investigates the performance and relative accuracy of four lattice-hole theory based equations of state in modeling and correlating the liquid density of pure refrigerants. following the gathering of a database of 5740 experimental liquid density datapoints of 36 pure refrigerants belonging to five different categories including cfcs, hcfcs, pfcs, hfcs and hfes, ranging from 6...