A complex of cerium(III) with 4-methyl-7-hydroxycoumarin was synthesized by mixing water solutions of cerium(III) nitrate and 4-methyl-7-hydroxycoumarin sodium salt in a metal-to-ligand molar ratio of 1:2. The complex was characterized and identified by elemental analysis, conductometry, IR, 1H and 13C NMR-spectroscopy, mass spectral data, DTA and TGA. Thermal analysis of the complex indicated ...

With rapid solidification following pulsed laser melting, we have measured the dependence on interface orientation of the amount of solute trapping of several group III, IV, and V elements (As, Ga, Ge, In, Sb, Sn) in Si. The aperiodic stepwise growth model of Goldman and Aziz accurately fits both the velocity and orientation dependence of solute trapping of all of these solutes except Ge. The s...

The interaction of 3,3-bis(1-methylimidazol-2-yl)propionate (BIMP) with dimethyltin(IV) dichloride (DMT), dibutyltin(IV) dichloride (DBT), and diphenyltin(IV) dichloride (DPT) is investigated at 25°C and 0.1 M ionic strength in water for dimethyltin(IV), and in a 50% dioxane-water mixture for dibutyltin(IV) and diphenyltin(IV). The stepwise formation constants of the 1 : 1 and 1 : 2 complexes f...

Mutation bias is one of the forces that may constrain the variation at microsatellite loci. Here, we study the dynamics of population statistics and the genetic distance between two populations under multiple stepwise mutations with linear bias and random drift. Expressions are derived for these statistics as functions of time, as well as at mutation-drift equilibrium. Applying these expression...

The Natriuretic and Endogenous DigitalisLike Factors (EDLFs) are disclosed to be cyclomeric and macroring closed derivatives of the inorganic carbon suboxide. The macrocyclic cyclohexamer with six carbon suboxide units has a molar mass of 408.2 Da, as previously been found for the EDLF of animal origin. The anhydrous cyclohexameric factor is lipophilic but is transformed into more hydrophilic d...

Normal form procedure This is the stepwise ‘simplification’ by changes of coordinates, of the Taylor series at an equilibrium point, or of similar series at periodic or quasi-periodic solutions. Preservation of structure The normal form procedure is set up in such a way that all coordinate changes preserve a certain appropriate structure. This applies to the class of Hamiltonian or volume prese...

Advanced learning environments such as intelligent tutoring systems for algebra, logic, programming, physics, etc. let a student practice with stepwise exercises, and support a student solving such exercises by providing feedback. These environments usually provide various types of feedback, for example about the correctness of a step, common errors, hints about how to proceed, or complete work...

In real soils the interaction of humic substances with clay minerals often occurs participation metal cations. The adsorption fulvic acids (FA) solution and their solutions in presence heavy ions (Pb or Zn) on two (kaolinite bentonite) was investigated by measurement optical density changes equilibrium solutions. FA bentonite at concentrations 0.05–1 g/L proceeds according to polymolecular mech...