A mild method for the regioselective C2-bromination of fused azine N-oxides is presented, employing tosic anhydride as the activator and tetra-n-butylammonium bromide as the nucleophilic bromide source. The C2-brominated compounds are produced in moderate to excellent yields and with excellent regioselectivity in most cases. The potential extension of this method to other halogens, effecting C2...

the interactions of β-lactoglobulin ab in the presence of cationic surfactants such as cetyltrimethylammonium bromide and cetyltrimethylammonium p-toluenesulfonate have been investigated using a variety of experimental techniques such as conductivity, uv-vis spectrophotometry and fluorimetry. the conductivity of surfactants aqueous solutions with β-lactoglobulin shows that the cmc of cationic s...

Biofilm is a significant cause for membrane fouling. Antibacterial-coated surfaces can inhibit biofilm formation by killing bacteria. In this study, polyethersulfone (PES) microfiltration membrane was photografted by four antibiotic quaternary ammonium compounds (QACs) separately, which were synthesized from dimethylaminoethyl methacrylate (DMAEMA) by quaternization with butyl bromide (BB), oct...

The structure of the title salt, (C(6)H(14)N)(2)[CuBr(4)], is built up from cyclo-hexyl-ammonium cations and tetra-bromidocuprate anions, the latter being located on an inversion center. In the crystal, anions and cations are inter-connected by N-H⋯Br hydrogen bonds, forming ribbons parallel to [0-11].

Four mol-ecular salts made from hexa-methyl-ene-tetra-minium and 2-chloro-4-nitro-benzoate have been synthesized and are reported, namely ammonium hexa-methyl-ene-tetra-minium bis-(2-chloro-4-nitro-benzoate), NH4+·C6H13N4+·2C7H3ClNO4-, (I), hexa-methyl-ene-tetra-minium hydrogen bis-(2-chloro-4-nitro-benzoate), 0.5C6H13N4+·C7H3.50ClNO4-, (II), hexa-methyl-ene-tetra-minium 2-chloro-4-nitro-benzoa...

In the title compound, [Sn2(CH3)6(NCS)2(C24H22N4)], the 1,2,3,4-tetra-kis-(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The Sn(IV) atom in the mol-ecule shows a distorted trans-trigonal-bipyramidal coordination with the methyl groups in equatorial positions. The mol-ecul...

1-butyl-3-methylimidazolium bromide ([bmim]br) as an ionic liquid promoted selectively oxidation of aliphatic and aromatic sulfides to the corresponding sulfoxides and the oxidative coupling of thiols to disulfides by nabro3 in excellent yields under neutral conditions.

In the title mol-ecule, C21H20BrClN6O2, the chloro-substituted benzene ring forms a dihedral angle of 77.84 (7)° with the tetra-zole ring and the bromo-substituted ring forms a dihedral angle of 43.95 (6)° with the imidazole ring. The dihedral angle between the tetra-zole and imidazole rings is 67.42 (8)°. The terminal methyl group of the butyl substituent is disordered over two sets of sites, ...

In the title mol-ecular salt, (C(6)H(16)N)(2)[CuCl(4)], the Cu(II) ion adopts an extremely distorted tetra-hedral coordination geometry. All the ammonium H atoms are involved in N-H⋯Cl hydrogen bonds, which serve to link the cations and anions into chains propagating along the c-axis direction.

The -SCH(2)CH(2)CH(2)CH(2)S- portion of the title compound, C(12)H(14)N(2)S(2), adopts an extended zigzag conformation. The angles at the tetra-hedral carbon atoms are marginally increased [113.63 (12)° and 111.38 (17)° for S-C-C and C-C-C respectively] from the idealized tetra-hedral angle. The mol-ecule lies on an inversion center located at the mid-point of the butyl chain. In the crystal, t...