The effectiveness of a material to adequately seal the root canal space is related to its physical properties and handling characteristics. Since the introduction of the warm vertical compaction technique, the thermoplastic compaction of canal spaces has been broadly advocated. Warm gutta percha can be easily Rheological characterization of thermoplasticized injectable gutta percha and resilon

In this proof of concept study we demonstrate direct utilization of limonene containing waste product orange peel as starting material for a biocatalytic cascade reaction. The product of this cascade is chiral carvolactone, a promising building block for thermoplastic polymers. Four different concepts were applied to augment limonene availability based on either water extraction solely, additio...

Polymer, heal thyself! Supramolecular ABA triblock copolymers formed by dimerization of 2-ureido-4-pyrimidinone (UPy) end-functionalized polystyrene-b-poly(n-butyl acrylate) (PS-b-PBA) AB diblock copolymers have been synthesized, resulting in a self-healing material that combines the advantageous mechanical properties of thermoplastic elastomers and the dynamic self-healing features of supramol...

We report a simple, effective method of managing displaced unilateral condylar fractures with occlusal disruption using vacuum-formed thermoplastic foil splints with bonded wire cleats. The cleats enable intermaxillary fixation in the form of orthodontic elastics to be used, which guide then maintain the occlusion in centric relation. A case is presented in which this technique was used success...

We present a novel approach for the ultra-rapid direct patterning of complex three-dimensional, stacked polystyrene (PS) microfluidic chips. By leveraging the inherent shrinkage properties of biaxially pre-stressed thermoplastic sheets, microfluidic channels become thinner and deeper upon heating. Design conception to fully functional chips can thus be completed within minutes.

To investigate the inter- and intra-fraction motion associated with the use of a low-cost tape immobilization technique as an alternative to thermoplastic immobilization masks for whole-brain treatments. The results of this study may be of interest to clinical staff with severely limited resources (e.g., in low-income countries) and also when treating patients who cannot tolerate standard immob...

Atomic force microscopy (AFM) is used to study the phase separation process occurring in block copolymers in the solid state. The simultaneous measurement of the amplitude and the phase of the oscillating cantilever in the tapping mode operation provides the surface topography along with the cartography of the microdomains of different mechanical properties. This technique thus allows to charac...

Self-healing in orthopedic bone cement is demonstrated with a novel thermoplastic solvent-bonding approach. Low toxicity solvent-filled microcapsules, embedded in a commercial acrylic bone cement matrix, enable recovery of up to 80% of the virgin fracture toughness of the cement at room and body temperature conditions without external stimuli or human intervention.

A simplified method for making shadowed thermoplastic negative replicas of fibrous materials was developed. Through this technique, fine details of the morphology of the wool fiber, before and after treatment, were clearly revealed by the electron microscope. The structural implications of the electron micrographs are discussed with respect to the subject of wear and in reference to the observa...