Functionalization of metal–organic frameworks (MOFs) is critical in exploring their structural and chemical diversity for numerous potential applications. Herein, we report multiple approaches the tandem postsynthetic modification (PSM) various MOFs derived from Zr(IV), Al(III), Zn(II). Our current work based on our efforts to develop a wide range MOF platforms with dynamic functional nature th...

Abstract The interaction of eosin B dye from aqueous solution with MIL-100(Fe) and functionalized metal–organic frameworks (MOFs) is reported in this study. was prepared thioglycolic acid (TH) ethylenediammine (ED) separately by incorporating the thiol (–SH) amine (–NH 2 ) group functionalizing agents into open metal sites to obtain acidic (TH-MIL-100) basic (ED-MIL-100) forms MOF respectively....

Gold nanoparticles have led to numerous advances in nanomaterial-based sensors and biomedical technologies owing their chemical inertness outstanding physiochemical optical properties. are still considered one of the most promising types nanomaterials various fields, including drug delivery, cancer therapy, biomolecule detection, high-accuracy diagnosis. Surface functionalization gold with liga...

AIM To determine dynamic thiol/disulphide homeostasis in celiac disease and to examine the associate with celiac autoantibodies and gluten-free diet. METHODS Seventy three patients with celiac disease and 73 healthy volunteers were enrolled in the study. In both groups, thiol/disulphide homeostasis was examined with a new colorimetric method recently developed by Erel and Neselioglu. RESULT...

toluene and benzene were eliminated using multi-walled carbon nanotubes (mwcnts). in order to investigate influence of acid treatment on the mwcnts adsorption capacities, the mwcnts were functionalized by nitric acid (10 m) under reflux conditions for 2 h. fourier transform infrared (ftir) and raman spectroscopy were employed to confirm the formation of functional groups on the nanotubes surfac...

In situ hydrogelation of injectable precursors upon biological stimulus is relevant to generate hydrogels under mild conditions and, potentially, at a side interest. Here, it shown that hydrolytic enzymes can be used initiate the formation covalent hydrogel networks, realizing cleavage-leading-to-gelation strategy. For this purpose, two-component system used, consisting 4-arm polyethylene glyco...

Photocurable gelatin-based hydrogels have established themselves as powerful bioinks in tissue engineering due to their excellent biocompatibility, biodegradability, light responsiveness, thermosensitivity and bioprinting properties. While gelatin methacryloyl (GelMA) has been the gold standard for many years, thiol-ene hydrogel systems based on norbornene-functionalized (GelNB) a thiolated cro...

C-H functionalization is a very active research field that has attracted the interest of scientists from many disciplines. This Outlook describes the collaborative efforts within the NSF CCI Center for Selective C-H Functionalization (CCHF) to develop catalyst-controlled selective methods to enhance the synthetic potential of C-H functionalization.