This letter describes a method for forming Ru nanoclusters on oxide anode surfaces during the initial stages of solid oxide fuel cell operation, ielding improved anode performance without additional processing steps. Transmission electron microscope and X-ray photoelectron spectroscopy ◦ bservations showed that Ru nanoclusters precipitated onto La0.8Sr0.2Cr0.82Ru0.18O3−δ surfaces after exposure...

Abstract In the FFC-Cambridge process, cathodic dissociation of oxide and CO/CO 2 production on carbon anode is basis for metal in a CaCl bath. Using an inert intermetallic anode, CO evolution can be eliminated altogether with acceleration electro-reduction kinetics. presence TiO suffers from slow reduction kinetics to Ti metal, which enhanced significantly by incorporation alkali species pelle...

Transition metal oxides show great promise as Earth-abundant catalysts for the oxygen evolution reaction in electrochemical water splitting. However, progress in the development of highly active oxide nanostructures is hampered by a lack of knowledge of the location and nature of the active sites. Here we show, through atom-resolved scanning tunnelling microscopy, X-ray spectroscopy and computa...

Interfacial interactions between late transition metal/metal oxide nanoparticles and oxide supports impact catalytic activity and stability. Here, we report the use of isothermal titration calorimetry (ITC), electron microscopy and density functional theory (DFT) to explore periodic trends in the heats of nanoparticle-support interactions for late transition metal and metal oxide nanoparticles ...

Titanium oxide catalysts were implanted with various transition-metal ions by a high-voltage acceleration technique, then calcined in O2 at around 723 K to produce photocatalysts capable of absorbing visible light, the extent of the red shift depending on the amount and kind of metal ions implanted. Such metal ion-implanted titanium oxide photocatalysts, specifically using Cr or V ions, were su...

In this study we report on the development and operational data of a metal-supported solid oxide fuel cell with a thin film electrolyte under varying conditions. The metal-ceramic structure was developed for a mobile auxiliary power unit and offers power densities of 1 W/cm² at 800 °C, as well as robustness under mechanical, thermal and chemical stresses. A dense and thin yttria-doped zirconia ...

Reports of metallic behavior in two-dimensional (2D) systems such as high mobility metal-oxide field effect transistors, insulating oxide interfaces, graphene, and MoS2 have challenged the well-known prediction of Abrahams, et al. that all 2D systems must be insulating. The existence of a metallic state for such a wide range of 2D systems thus reveals a wide gap in our understanding of 2D trans...

Titanium dioxide (TiO2) nanotube and its hybrid nanotubes (with various metal oxides such as Ta2O5, Nb2O5, ZrO2, and SiO2) were fabricated by the sol-gel polymerization in the ethanol gels formed by simple L-lysine-based organogelator. The self-assembled nanofibers (gel fibers) formed by the gelator functioned as a template. The different calcination temperatures gave TiO2 nanotubes with variou...

A stochastic model of the resistive switching mechanism in bipolar metal-oxide-based resistive random access memory RRAM is presented. The distribution of electron occupation probabilities obtained is in good agreement with previous work. In particular, it is shown that a low occupation region is formed near the cathode. Our simulations of the temperature dependence of the electron occupation p...