Renewable energy sources have gained ultimate urgency due to the need of the preservation of the environment for a sustainable development. Pyrolysis is an ultimate promising process in the recycling and acquisition of precious chemicals from wastes. Here, the co-pyrolysis of hazelnut shell with ultra-high molecular weight polyethylene was carried out catalytically and noncatalytically at 500 a...

Bimodal polyethylene is generated from a single immobilized catalyst on support under set of reaction conditions without introducing chain transfer agents. Using rac-ethylenebis(1-indenyl)zirconium dichloride [(EBI)ZrCl2] nickel-containing layered double hydroxide (LDH) produces two distinct molecular weight distributions. The ratio these fractions can be tuned by varying the LDH as well changi...

The synthesis and characterization of a series of dibenzhydryl-based α-diimine Ni(II) complexes bearing a range of electron-donating or -withdrawing groups are described. Polymerization with ethylene is investigated in detail, involving the activator effect, influence of polymerization conditions on catalyst activity, thermal stability, polymer molecular weight and melting point. All of these N...

We considered the formation of integrated biostable coating on surface several polymers using original gas-phase fluorination technology. The effectiveness modification low-density polyethylene (LDPE) and polypropylene (PP) was confirmed by corresponding changes in absorption spectra infrared radiation with modified samples. quality ultrahigh molecular weight (UHMWPE) nitrile butadiene rubber (...