Some new compounds based on bis-benzimidazole moieties have been synthesized and characterized by IR and NMR spectroscopies. The ability of 3a in transition metal cation sensing such as Co2+, Ni2+, Zn2+, Mn2+, Fe2+ and Cu2+ have been investigated by Uv-vis and fluorescence spectroscopy in methanol solvent. The complexation constants and complex stoichiometry of Cu2+ have been determined. The ex...

Reactive and pharmaceutical-grade heparins were used as biologically compatible reducing and stabilizing agents to photochemically synthesize colloidal gold nanoparticles. Aggregates and anisotropic shapes were obtained photochemically under UV black-light lamp irradiation (λ = 366 nm). Heparin-functionalized gold nanoparticles were characterized by Scanning Electron Microscopy and UV-Vis spect...

Polypyrrole nanoparticles were synthesized by chemical polymerization method using ammonium persulphate as an oxidant. The synthesized polypyrrole nanoparticles were characterized by FT-IR, UV-Visible, FESEM and CV. The structure of polypyrrole nanoparticles were confirmed by FT-IR spectroscopy. The UV-Vis spectra of polypyrrole nanoparticles show π-π* and n-π* transitions. The morphological pr...

zinc oxide nanotubes were prepared by a hydrothermal method using zinc nitrate as a precursor. The synthesized nanotubes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and their optical properties were characterized using UV -visible spectroscopy. The XRD analysis confirme...

In order to characterize the pollution discharged into the Moselle River and some of its tributaries, spectroscopic techniques, namely UV-vis spectroscopy and synchronous fluorescence spectroscopy, have been combined. UV-visible spectra were analysed using the maximum of the second derivative at 225 nm (related to nitrates), the SUVA254 and E2/E3 indices (related to the nature of organic matter...

Rhodococcus jostii RHA1 peroxidase DypB has been recently identified as a bacterial lignin peroxidase. The dypB gene is cotranscribed with a gene encoding an encapsulin protein, which has been shown in Thermotoga maritima to assemble to form a 60-subunit nanocompartment, and DypB contains a C-terminal sequence motif that is thought to target the protein to the encapsulin nanocompartment. R. jos...

One-electron reduction of the "extended viologen" dication 1 yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2.

Ultraviolet light induced changes in polyimide liquid-crystal alignment films were investigated. Infrared, UV-visible, x-ray photoelectron spectroscopy, and electron-spin-resonance measurements indicated that bond breaking and subsequent oxidation reactions occur in polyimide films ~SE7210, OCG284, DuPont 2555 and 2540! during the broadband UV illumination in air. Mechanical rubbing has no effe...

The self-organization of monolayer gold nanoparticles (AuNPs) on 3-aminopropyltriethoxysilane (APTES)-functionalized glass substrate is reported. The orientation of APTES molecules on glass substrates plays an important role in the interaction between AuNPs and APTES molecules on the glass substrates. Different orientations of APTES affect the self-organization of AuNps on APTES-functionalized ...