The metastability of some phases of CsHSO4 and RbH2PO4 is due to the volume decrease at an endothermic phase transition which “locks in” the metastability in question. Water adsorption, which removes these metastabilities, probably exerts a “wedge-like” force which expands the lattice spacing in the surface layer, thus facilitating the start of the phase transition. The induction time and the z...

The isotropic–nematic transition of nano-rod monolayers with fore–aft symmetry is second order, in stark contrast to the first-order phase transition explained by Onsager [L. Onsager, Ann. (N.Y.) Acad. Sci. 51 (1949) 627] for rods in three dimensions. Here we show that the coupling of a dipole potential to excluded volume is sufficient to re-instate a first-order phase transition of rods confin...

Internal imaging using index matching, and sensitive volume measurement, are used to investigate the spatial order and dynamics of a deep disordered layer of spheres sheared under a fixed load. Shearing triggers a crystallization transition accompanied by a step compaction event. The delay preceding the transition depends strongly on the layer thickness and can require a translation of about 10...

We study by molecular dynamics computer simulation a binary soft-sphere mixture that shows a pronounced difference in the species' long-time dynamics. Anomalous, power-law-like diffusion of small particles arises that can be understood as a precursor of a double-transition scenario, combining a glass transition and a separate small-particle localization transition. Switching off small-particle ...

The 125th anniversary of Osborne Reynolds' seminal publication on the transition to turbulence in pipe flow offers an opportunity to survey our understanding of the nature of the transition. Dynamical systems concepts, computational methods and dedicated experiments have helped to elucidate some of Reynolds' observations and to extract new quantitative characteristics of the transition. This in...

The 125th anniversary of Osborne Reynolds’ seminal publication on the transition to turbulence in pipe flow offers an opportunity to survey our understanding of the nature of the transition. Dynamical systems concepts, computational methods and dedicated experiments have helped to elucidate some of Reynolds’ observations and to extract new quantitative characteristics of the transition. This in...

The phase behavior of helical packings of thermoresponsive microspheres inside glass capillaries is studied as a function of the volume fraction. Stable packings with long-range orientational order appear to evolve abruptly to disordered states as the particle volume fraction is reduced, consistent with recent hard-sphere simulations. We quantify this transition using correlations and susceptib...

We have numerically studied the trapping problem in a two-dimensional lattice where particles are continuously generated. We have introduced interaction between particles and directionality of their movement. This model presents a critical behaviour with a rich phase structure similar to spin systems. We interpret a change in the asymptotic density of particles as a phase transition. For high d...

Early Xenopus laevis embryogenesis is a robust system for investigating mechanisms of developmental timing. After a series of rapid cell divisions with concomitant reductions in cell size, the first major developmental transition is the midblastula transition (MBT), when zygotic transcription begins and cell cycles elongate. Whereas the maintenance of a constant nuclear-to-cytoplasmic (N/C) vol...

Depending on solution conditions, beta-lactoglobulin can exist in one of its six pH-dependent structural states. We have characterized the acid and basic-induced conformational transitions between these structural states over the pH range of pH 1 to pH 13. To this end, we have employed high-precision ultrasonic and densimetric measurements coupled with fluorescence and CD spectroscopic data. Ou...