We combine ab initio density functional and quantum transport calculations based on the nonequilibrium Green's function formalism to compare structural, electronic, and transport properties of Mo6S6-xIx nanowires with carbon nanotubes. We find systems with x=2 to be particularly stable and rigid, with their electronic structure and conductance close to that of metallic (13,13) single-wall carbo...

The novel phenomenon of chiral tunneling in metallic single-wall carbon nanotubes is considered. It is induced by the interplay of electrostatic and pseudomagnetic effects in electron scattering in chiral nanotubes and is characterized by an oscillatory dependence of the electron transmission probability on the nanotube chiral angle and the strength of the scattering potential. The appearance o...

Nano-plasticity of thin single-wall carbon nanotubes under uniaxial compression is investigated through generalized tight-binding molecular dynamics (GTBMD) and ab-initio electronic structure methods. A novel mechanism of nano-plasticity of carbon nanotubes under uniaxial compression is observed in which bonding geometry collapses from a graphitic (sp 2) to a localized diamond like (sp 3) recon...

We have studied the trigonal warping effect in metallic carbon nanotubes using resonance Raman scattering and examining the G0-band profile for individual metallic single-wall carbon nanotubes. We show that the observed splitting in the G0-band phonon spectra is directly correlated with the splitting in the singularities of the joint density of electronic states, i.e., detailed information abou...

Propagation of dipolar-coupled transverse domain walls in a permalloy/non-magnetic/permalloy trilayer was investigated using micromagnetic modeling. Circulating stray fields meant that the adopted composite structure with behavior analogous to seen nanotubes. Wall velocities were sensitive chirality field circulation, most favored enhanced by 32% compared individual constituent layers just belo...

A highly sensitive and stable tris(2,2′-bipyridyl)ruthenium(II) (Ru(bpy)3) electrogenerated chemiluminescence (ECL) sensor was developed based on carbon nanotube (CNT) dispersed in mesoporous composite films of sol–gel titania and perfluorosulfonated ionomer (Nafion). Single-wall (SWCNT) and multi-wall carbon nanotubes (MWCNT) can be easily dispersed in the titania–Nafion composite solution. Th...

A qualitative description of the electronic structure of single-wall carbon nanotubes from a chemical perspective is presented using real-space orbital representations and traditional concepts of aromaticity, orbital symmetry and frontier orbitals. This unusual view of carbon nanotubes allows us to merge the solid-state physics description of band structures with the molecular orbitals framewor...

The realization of high-performance electrical devices incorporating single-wall carbon nanotubes critically depends on the minimization of charge transport barriers in the tubes and at the contacts. Herein we demonstrate photocurrent imaging as a fast and effective tool to locate such barriers within individual metallic nanotubes contacted by metal electrodes. The locally induced photocurrents...

We have performed electroabsorption spectroscopy on micelle-wrapped single-wall carbon nanotubes. In semiconducting nanotubes, many oscillating structures composed of the increase and decrease of absorption are observed in the spectra in the region of the first and second absorption bands, E11 and E22. The spectral shape is reproduced mainly by the second-derivative curve of the absorption spec...

The unusual one-dimensional properties of phonons in crystalline arrays of carbon nanotubes is presented. The main technique for probing the phonon spectra is Raman spectroscopy and the many unique and unusual features of the Raman spectra of carbon nanotubes are highlighted. Various features of the first-order Raman spectra are emphasized, with regard to their 1D behavior and special character...