نتایج جستجو برای: zif 67
تعداد نتایج: 71974 فیلتر نتایج به سال:
در سالهای اخیر، یافتن یک سوخت جایگزین به دلیل محدودیت منابع سوختهای فسیلی، افزایش قیمت نفتخام و اهمیت نشر گازهای گلخانهای بسیار مورد توجه قرار گرفته است. بنابراین، تلاش برای کشف و بهرهبرداری از سوختهای سبز بهطور پیوسته افزایش یافته است. بایودیزل از مهمترین اعضای این خانواده از سوختها است. در این پژوهش، فرایند استریشدن تولید بایودیزل برای نخستین بار با نانوساختار چارچوب ایمیدازولی زئول...
Lead halide perovskites have been regarded as promising materials for fabrication of high-performance photodetectors (PDs). However, spin-coated perovskite thin films generally suffered from high-density grain boundaries and defect states, which severely deteriorated the performance stability resulting PDs. Fortunately, above issues can be effectively solved via additive assisted metal ions dop...
Gas transport through metal-organic framework membranes (MOFs) was switched in situ by applying an external electric field (E-field). The switching of gas permeation upon E-field polarization could be explained by the structural transformation of the zeolitic imidazolate framework ZIF-8 into polymorphs with more rigid lattices. Permeation measurements under a direct-current E-field poling of 50...
While bulk-sized metal-organic frameworks (MOFs) face limits to their utilization in various research fields such as energy storage applications, nanoarchitectonics is believed to be a possible solution. It is highly challenging to realize MOF nanobubbles with monocrystalline frameworks. By a spatially controlled etching approach, here, we can achieve the synthesis of zeolitic imidazolate frame...
Zeolitic imidazolate frameworks (ZIFs), a subclass of metal organic frameworks, are built of tetrahedral metal ions bridged by imidazolates. They have permanent porosity and relatively high thermal and chemical stability, which make them attractive candidates for many industrial applications. In recent years, significant progress has been made in developing ZIFs into membranes and thin films fo...
We fabricated a highly efficient (with a solar-to-electricity conversion efficiency (η) of 8.1%) Pt-free dye-sensitized solar cell (DSSC). The counter electrode was made of cobalt sulfide (CoS) nanoparticles synthesized via surfactant-assisted preparation of a metal organic framework, ZIF-67, with controllable particle sizes (50 to 320 nm) and subsequent oxidation and sulfide conversion. In con...
Although strategies of compositing noble materials and Zeolitic imidazolate frameworks (ZIFs) have been used to enhance the performance ZIF-based surface-enhanced Raman scattering (SERS) substrates, enhancement process still remains unclear sampling with powder-form substrates is challenging for practical applications. In this study, a flexible SERS substrate silver (Ag) nanoparticle decorated ...
We report here, a strategy to prepare Pt/Pd nanoparticles decorated with Co-N-C materials, where was obtained via pyrolysis of ZIF-67 directly. As-prepared Pt/Pd/Co-N-C catalysts showed excellent ORR performance, offered higher limit current density (6.6 mA cm?2) and similar half-wave potential positive (E1/2 = 0.84 V) compared commercial Pt/C. In addition an activity, it also exhibits robust d...
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