A complex processing variant for pyrite cinders, i.e., the technogenic waste generated in production of sulfuric acid, was proposed. This method provided preliminary chemical activation initial raw materials that comprised thermal treatment with a sodium bicarbonate solution and resulted structural phase changes separate minerals. Due to activation, it possible nonferrous metals into products (...

There are many remediating methods for the polluted soils but only phytoremediation is a cost effective, environmental friendly, aesthetically pleasing approach that is most suitable for many countries. The purpose of this study was to investigate the potential of native plants for phytoremediation of contaminated soils with lead, zinc, cadmium and nickel in the rangelands around National Lead ...

In the catalysis of the hydration of carbon dioxide and dehydration of bicarbonate by human carbonic anhydrase II (HCA II), a histidine residue (His64) shuttles protons between the zinc-bound solvent molecule and the bulk solution. To evaluate the effect of the position of the shuttle histidine and pH on proton shuttling, we have examined the catalysis and crystal structures of wild-type HCA II...

Hyperaccumulators tolerate and accumulate extraordinarily high concentrations of heavy metals. Content of the metal chelator nicotianamine (NA) in the root of zinc hyperaccumulator Arabidopsis halleri is elevated compared with nonhyperaccumulators, a trait that is considered to be one of the markers of a hyperaccumulator. Using metabolite-profiling analysis of root secretions, we found that exc...

In this study bio-hydrogen and bioethanol were produced from dry biomass of water hyacinth by microbial fermentation under influence of zinc oxide nanoparticles. For fermentative bio-hydrogen production biomass was first pretreated and then saccharified into fermentable sugars by enzymes. Sugars of enzymatic hydrolysis were xylose and glucose with concentration of 9.0% and 8.0% respectively. Fo...

Manganese homeostasis involves coordinated regulation of specific proteins involved in manganese influx and efflux. However, the proteins that are involved in detoxification/efflux have not been completely resolved nor has the basis by which they select their metal substrate. Here, we compared six proteins, which were reported to be involved in manganese detoxification/efflux, by evaluating the...

Transcription factor IIIA is a very extensively studied eukaryotic gene specific factor. It is a special member of the zinc finger family of nucleic acid binding proteins with multiple functions. Its N-terminal polypeptide (280 amino acid residue containing peptide; finger containing region) carries out sequence specific DNA and RNA binding and the C-terminal peptide (65 amino acid residue cont...