Metal-organic frameworks (MOFs) possess the features of highly porosity-tunable and electronic-tunable structures. Taking advantages these merits, we successfully installed high-valence W6+ ions onto Ti-oxo clusters MIL-125(Ti) (W-MIL-125). The which form a W-O-Ti structure trigger metal-to-cluster charge transfer (MCCT), together with an enhanced light absorption. Structural spectroscopic char...

A vicinal rutile TiO2(110) crystal with a smooth variation of atomic steps parallel to the [1-10] direction was analyzed locally with STM and ARPES. The step edge morphology changes across the samples, from [1-11] zigzag faceting to straight [1-10] steps. A step-bunching phase is attributed to an optimal (110) terrace width, where all bridge-bonded O atom vacancies (Obr vacs) vanish. The [1-10]...

The aim of this paper is to compare the bioactive behavior generated by two different surface treatments on Ti-6Al-7Nb previous to the implant in the animal knee. One of the treatments consists in soak the sample with NaOH and followed by a subsequent heat treatment. The other treatment consists in immersion for 19 days in a SBF solution with additional PAW1 biovitroceramic (particles under 20 ...

The parallel nano-scanning calorimeter (PnSC) is a silicon-based micromachined device for calorimetric measurement of nanoscale materials in a high-throughput methodology. The device contains an array of nanocalorimeters. Each nanocalorimeter consists of a silicon nitride membrane and a tungsten heating element that also serves as a temperature gauge. The small mass of the individual nanocalori...

A series of mixed iron and titanium oxide coprecipitates ranging in composition between 0 < Ti/Ti + Fe < 1 was synthesized and aged under varying conditions of pH, temperature and time in order to establish a working model for pedogenic titanium and titano-ferric oxides. X-ray powder diffraction (XRD), selective chemical dissolution, magnetic susceptibility, charge distribution and electron opt...

Mineral analysis of forage from a nitrogen (N) fertilizer, field study produced unexpectedly high iron (Fe) concentrations which were correlated with the N fertilizer level (r2=.92) and the percentage N in the forage (r2 =.94). The high Fe values were presumed to be associated with dust on the leaves. The objective of this study was to determine the level of soil contamination on the forage sam...

Combinatorial nanocalorimetry and synchrotron x-ray diffraction were combined to study the martensite-austenite (M-A) phase transformation behavior of Ni-Ti-Hf shape memory alloys. A thin-film library of Ni-Ti-Hf samples with a range of compositions was deposited on a parallel nano-scanning calorimeter device using sputter deposition. Crystallization of each amorphous as-deposited sample by loc...

The effects of fluoride concentrations and pH on the corrosion behavior of pure titanium, Ti-6Al-4V, Ti-6Al-7Nb alloys and a new Ti alloy adding palladium, which is expected to promote a repassivation of Ti were examined by anodic polarization and corrosion potential measurements. The amount of dissolved Ti was analyzed by inductively coupled plasma mass spectroscopy. The surface of the specime...