Ru is considered as an effective active species for N2O decomposition; however, there is disagreement about which ruthenium species is key for catalytic activity. In order to understand the role of Ru species in N2O decomposition, Ru/Al2O3 (Ru/Al2O3-H2, Ru/Al2O3-NaBH4, Ru/Al2O3-air) catalysts with different ratios of metallic Ru were prepared and evaluated for their catalytic activities. Variou...

the no removal over oxide sorbents (k2o/al2o3 , cao/al2o3 and bao/al2o3) at a loading of up to 25 wt.% was investigated using a synthetic diesel exhaust gas containing  1,000 ppm no, 1000 ppm iso-butane (i-c4h10), 8% o2 and n2 balance. the reactor was operated  at 250 oc to 450 oc for the activity study. no was effectively stored (removal efficiencies between 30-60 %) as nitrate under experimen...

The preparation of Ru nanoparticles supported on γ-Al2O3 followed by chemical reduction using RuCl3 as a precursor is demonstrated, and their properties are compared to prepared impregnation with Ru3(CO)12 subsequent thermal decomposition. resulting from slightly larger (1.2 vs. 0.8 nm). In addition, were deposited Stöber SiO2 both deposition techniques. These particles than the ones (2.5 3.4 n...

Although the response of macrophages to polyethylene debris has been widely studied, it has never been compared with the cellular response to ceramic debris. Our aim was to investigate the cytotoxicity of ceramic particles (Al2O3 and ZrO2) and to analyse their ability to stimulate the release of inflammatory mediators compared with that of high-density polyethylene particles (HDP). We analysed ...

The quality of synthesized materials is affected by various factors such as the prehistory substances used and synthesis technology. Most methods for synthesizing luminescent ceramics based on metal oxides rely high-temperature heating to facilitate necessary exchange elements between precursor particles. However, a promising alternative method involves direct application powerful high-energy r...

It is of great importance to develop a spherical γ-alumina support with high hydrothermal stability be used in platinum reforming catalyst processes. The porous pseudo-boehmite powder surface area was first synthesized via simple separate nucleation and aging steps method, then as precursor produce γ-Al2O3 an oil–ammonia column method. as-synthesized has substantially greater specific 336.0 m2·...

Gold nanoparticles on Al2O3-coated gold films are presented as a chemically and thermally robust platform for molecular sensing. Single particle spectroscopy as a function of Al2O3 coating thickness shows reproducible gold nanoparticle scattering spectra in the range from 690 to 610 nm as the Al2O3 thickness increases from 0 to 3.4 nm. Numerical simulation of these structures indicates that sur...

Advanced ceramic materials are gradually becoming very important for their superior properties such as high hardness, wear resistance, chemical resistance, and high strength to weight ratio. But machining of advanced ceramic like Al2O3-ceramics is very difficult by any well known and common machining processes. Normally, cleavages and triangular fractures generate when machining of these materi...

ZnO/Al2O3 multilayers were prepared by alternating atomic layer deposition (ALD) at 150°C using diethylzinc, trimethylaluminum, and water. The growth process, crystallinity, and electrical and optical properties of the multilayers were studied with a variety of the cycle ratios of ZnO and Al2O3 sublayers. Transparent conductive Al-doped ZnO films were prepared with the minimum resistivity of 2....

This work reports on recent advances in the deposition of non-wettable coatings with high water contact angles (WCAs). We propose a simple and easily-controlled method for fabricating different types of nanoestructured films of Al2O3 with hydrophobic properties by Physical Vapour Deposition (PVD). The films have been deposited over three types of hydrophilic substrates with very different value...