Both enantiomers of ferrocene [4]-helicenequinone 6, showing planar and helical chiralities, have been synthesized with very high optical purities using, as the key step, a kinetic resolution process between planar-chiral racemic ferrocene diene 2 and enantiopure sulfinyl benzoquinone (S)-3.

The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)°. The presence of an intra-molecular O-H⋯N hydrogen bond between the amido N atom and hydr-oxy H atom in the Schiff base ligand helps to stabilize the overall mol-ecular structure.

Clay minerals have been used in medicinal applications since Aboriginal times (Carretaro, 2002; Wilson, 2003). Clay poultices are used to heal wounds; people eat clays to coat stomach linings and soothe indigestion; animals eat clay containing trace elements (e.g., As) that can kill worms. The reasons that various clay minerals are effective as medicines may be as variable as the ailment, but b...

Composites based on high density polyethylene (HDPE), pine flour, and organic clay were made by melt compounding and then injection molding. The influence of clay on crystallization behavior, mechanical properties, water absorption, and thermal stability of HDPE/pine composites was investigated. The HDPE/pine composites containing exfoliated clay were made by a two-step melt compounding procedu...

A series of tantalum imido and amido complexes supported by a pyridine-linked bis(phenolate) ligand has been synthesized. Characterization of these complexes via X-ray crystallography reveals both C(s) and C(2) binding modes of the bis(phenolate)pyridine ligand, with complexes containing two or fewer strong pi-donor interactions from ancillary ligands giving C(s) symmetry, whereas three strong ...

With a view to applications in bifunctional catalysis, a modular cross-coupling strategy has been used to prepare amine bis(imidazolium) salts (3a and 3b) and an amine mono(imidazolium) salt (6) as precursors to chelating amido-NHC ligands. Treating the pro-ligands 3 with 3 equivalents of the bulky base KHMDS and Pd(OAc)(2) or PtCl(2)(COD) gave the four amido bis(N-heterocyclic carbene) pincer ...

Easily prepared and highly modular organic amide proligands have been used to synthesize a series of new bis(amidate)-bis(amido) Ti and Zr complexes via protonolysis. These complexes have been structurally characterized by NMR spectroscopy and X-ray crystallography. The solid-state molecular structures of these complexes indicate that the amidate ligands bind to the metal centers in an exclusiv...