نتایج جستجو برای: arrhenius plot
تعداد نتایج: 33565 فیلتر نتایج به سال:
Arrhenius-type plots for multifragmentation process, defined as the transverse energy dependence of the single-fragment emission-probability, (ln(1/pb) vs 1/ √ Et), have been studied by examining the relationship of the parameters pb and Et to the intermediate-mass fragment multiplicity 〈n〉. The linearity of these plots reflects the correlation of the fragment multiplicity with the transverse e...
Fractional factorial split-plot designs are widely used when it is impractical to perform fractional experiments in a completely random order. When there too many subplots per whole plot, or few plots, with replicated settings of the plot factors preferred. However, such an important study undeveloped literature. This paper considers WP from viewpoint clear effects. We investigate sufficient an...
In some experiments, the levels of factors are difficult to change; then fractional factorial split-plot (FFSP) designs suitable for selection. an FFSP design, divided into two classes—the whole plot (WP) and subplot (SP) factors. selection WP can affect that SP factors, which attracts much attention Paying more a new optimality criterion selecting such is proposed. The robustness proposed meth...
The validity of the Arrhenius equation for dissociative electron attachment rate coefficients is investigated. A general analysis allows us to obtain estimates of the upper temperature bound for the range of validity of the Arrhenius equation in the endothermic case and both lower and upper bounds in the exothermic case with a reaction barrier. The results of the general discussion are illustra...
Ionic transport in conventional ionic solids is generally considered to proceed via independent diffusion events or "hops." This assumption leads to well-known Arrhenius expressions for transport coefficients, and is equivalent to assuming diffusion is a Poisson process. Using molecular dynamics simulations of the low-temperature B1, B3, and B4 AgI polymorphs, we have compared rates of ion hopp...
A major mystery of glass-forming liquids is the non-Arrhenius temperature-dependence of the average relaxation time. This paper brie ̄y reviews the classical phenomenological models for non-Arrhenius behavior ± the free volume model and the entropy model ± and critiques against these models. We then discuss a recently proposed model according to which the activation energy of the average relaxat...
Molecular dynamics simulations have been used extensively to model the folding and unfolding of proteins. The rates of folding and unfolding should follow the Arrhenius equation over a limited range of temperatures. This study shows that molecular dynamic simulations of the unfolding of crambin between 500K and 560K do follow the Arrhenius equation. They also show that while there is a large am...
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