A crucial chain-branching step in autoignition is the decomposition of ketohydroperoxides (KHP) to form an oxy radical and OH. Other pathways compete with chain-branching, such as “Korcek” dissociation γ-KHP a carbonyl acid. Here we characterize formation its formic acid+acetone products from observations n-butane oxidation two complementary experiments. In jet-stirred reactor measurements, KHP...

At our laboratory extensive research has been conducted on the conversion of conventional Diesel cogeneration engines to operation on natural gas and biogas. In the framework of this research, a numerical simulation of a prechamber autoignition gas engine has been performed based on an experimental test case. With a simplified finiterate/eddy-dissipation model for the combustion of natural gas,...

The effect of steady strain on the transient autoignition of n-heptane at high pressures is studied numerically with detailed chemistry and transport in a counterflow configuration. Skeletal and reduced n-heptane mechanisms are developed and validated against experiments over a range of pressure and stoichiometries. Two configurations are investigated using the skeletal mechanism. First, the ef...