We have prepared and characterized a series of nonfluoro polymer composites with functional carbon additives such as graphite, candle soot and camphor soot which when mixed with EPF (Expanded Polystyrene Foam) matrices increase surface hydrophobicity. Water contact angles of >150° was observed on spin-cast composite film surfaces containing 3% camphor soot particles, compared to 89° in the abse...

A product analysis was m ade for the reaction between som e aromatic am ines and 3-bromocamphor (2), which was invariably transformed into camphor (3) and eventually aryliminocamphor. The tertiary N ,N -dim ethylanilines were oxidized through a com plex sequence o f couplings and rearrangements to a number o f diam ines of the diphenylm ethane type. Aniline (4) was also successful in the reduct...

Artemisia species possess pharmacological properties that are used for medical purposes worldwide. In this paper, the essential oils from the aerial parts of Artemisia nilagirica and Artemisia maritima from the western Indian Himalaya region are described. The main compounds analyzed by simultaneous GC/MS and GC/FID were camphor and 1,8-cineole from A. maritima, and camphor and artemisia ketone...

The 02, CO, and alkyl isocyanide-binding properties of a variety of vertebrate and invertebrate heme proteins have been compared in detail to those of protoheme mOn0-3-( 1-imidazoy1)-propylamide monomethyl ester in aqueous suspensions of soap micelles. The proteins examined include: cytochrome P-450,,, from Pseudomonasputida, beef heart cytochrome c oxidase, yeast cytochrome c peroxidase, a and...

Both diastereomeric isomers of epoxides with high optical purity are obtained when camphor N-methacryloylpyrazolidinone (1a) and N-tigloylpyrazolidinone (1b) are treated with a urea hydrogen peroxide/TFAA and methyl(trifluoromethyl)dioxirane, respectively.

We have synthesized two luminescent probes (D-4-Ad and D-8-Ad) that target cytochrome P450cam. D-4-Ad luminescence is quenched by Förster energy transfer upon binding (Kd = 0.83 muM) but is restored when the probe is displaced from the active site by camphor. In contrast, D-8-Ad (Kd approximately 0.02 muM) is not displaced from the enzyme, even in the presence of a large excess of camphor. The ...

In this work, pentanol and camphor blended with petrol in different proportions were used on spark-ignition engines to evaluate their performance, characteristics, emissions. Sample P0A (gasoline) showed the best specific fuel consumption for lower torque (3Nm) a value of 19.2Kg/kWh, sample P0B (100% pure gasoline 5% camphor) had higher (6Nm) 12.9Kg/Kwh. For brake thermal efficiency, gives effi...

Intramolecular cyclic etherification of 1,3-diols was investigated using iodine as a catalyst under solution reaction conditions. Compounds containing five-membered ether rings were obtained. Propella ether (11-oxatricyclo[4.4.3.0(1,6)]tridecane) was conveniently synthesized from 1,3-diol (6-(2-hydroxyethyl)spiro[4.5]decan-6-ol) in 97% yield via carbon skeleton rearrangement. Spiroethers and bi...

Both sonochemical and classical methodologies have been employed to convert camphor, 1,7,7-trimethylbicyclo[2.2.1]heptan-2-one, C₉H16C=O, into a number of derivatives including hydrazones, C₉H16C=N-NHAr 3, imines, C₉H16C=N-R 7, and the key intermediate nitroimine, C₉H16C=N-NO₂ 6. Reactions of nitroamine 6 with nucleophiles by classical methods provided the desired compounds in a range of yields...

background & aim: the genus tanacetum l. belongs to the family asteraceae and tribe anthemideae. according to the recent findings the number of tanacetum species in iran is 36, of which 12 are endemic. in this study the essential oil composition of tanacetum chiliophyllum var. oligocephalum was investigated for the first time.   experimental: the plant was collected during flowering stage f...