The chlorination of singly and multiply charged C60 cations has been investigated with the selected-ion flow tube technique. Observations are reported for the reactions of C60 , C60 21 and C60 z31 with Cl2, CCl4, CDCl3, CH2Cl2 and CH3Cl at room temperature (295 6 2 K) in helium at a total pressure of 0.35 6 0.02 Torr. C60 z1 and C60 21 were observed not to chlorinate, or react in any other way,...

In the past few decades, charge transfer in DNA has attracted considerable attention from researchers in a wide variety of fields ranging from bioscience and physical chemistry to nanotechnology. Charge transfer in DNA has been investigated using various techniques. Among them, time-resolved spectroscopic methods have provided information on chargetransfer dynamics in DNA, an important basis fo...

This review is focused on reactions that gate (control) the electron transfer between the primary quinone Q(A) and secondary quinone Q(B) in the photosynthetic reaction centre of Rhodobacter sphaeroides. The results on electron and proton transfer are discussed in relation to structural information and to the steered molecular dynamics simulations of the Q(B) ring flip in its binding pocket. De...

A phenomenological model of electron transfer reactions in solvents undergoing glass transition is discussed. The reaction constant cuts off slow polarization modes from the spectrum of nuclear thermal motions active on the observation time scale. The arrest of nuclear solvation in turn affects the reaction activation barrier making it dependent on the rate. The resultant rate constant is sough...

Pig kidney general acyl-CoA dehydrogenase (GAD) can be reduced by butyryl-CoA to form reduced enzyme and crotonyl-CoA. This reaction is reversible. Stopped-flow, kinetic investigations on GAD have been made, using the following reaction pairs: oxidized GAD/butyryl-CoA, oxidized GAD/crotonyl-CoA, oxidized GAD/alpha,beta-dideuteriobutyryl-CoA, reduced GAD/butyryl-CoA, and reduced GAD/crotonyl-CoA...

A theoretical analysis of the circuits for a nitrogen laser driven by the Blumlein or capacitor charge transfer transmission line is given in detail. The electrical characteristics of the charge line for a special case of resonant charging are discussed and the effects of various parameters on voltage and current are investigated. By using MICRO-CAP software the transient behavior of the curren...

The Ca* + CH3F --> CaF + CH3 reaction was photoinduced in 1:1 Ca...CH3F complexes formed in a supersonic expansion. The transition state of the reaction was explored by monitoring the electronically excited product, CaF, while scanning the laser that turns on the reaction. Moreover, the electronic structure of the Ca...FCH3 system was studied using ab initio methods by associating a pseudopoten...