(1)H NMR and isothermal titration calorimetry (ITC) experiments were employed to obtain reliable thermodynamic data for the formation of the 1:1 inclusion complexes of fullerenes C(60) and C(70) with the buckycatcher (C(60)H(28)). NMR measurements were done in toluene-d8 and chlorobenzene-d5 at 288, 298, and 308 K, while the ITC titrations were performed in toluene, chlorobenzene, o-dichloroben...

Photoionization cross sections of the phenyl radical to form the phenyl cation were measured using tunable vacuum ultraviolet synchrotron radiation coupled with photofragment translational spectroscopy. The phenyl radical was produced via 193- or 248-nm dissociation of chlorobenzene. At 10.0 eV, the photoionization cross sections for the phenyl radical averaged over product channels were found ...

The strong influence of solvents on the ordering of poly(3-dodecylthiophene) (P3DDT) due to edge-on oriented stacking, in the spin-coated thin film on the Si substrate, both near the substrate and away from it, depending upon the substrate surface nature, is observed from the X-ray reflectivity study. The absence of any appreciable amount of coil-like P3DDT chains (i.e. charge localized states)...