The crystal structures of the new isomorphous compounds iron(III) oxyfluorotellurate(IV), FeTeO(3)F, gallium(III) oxyfluorotellurate(IV), GaTeO(3)F, and chromium(III) oxyfluorotellurate(IV), CrTeO(3)F, consist of zigzag chains of MO(4)F(2) distorted octahedra alternately sharing O-O and F-F edges and connected via TeO(3) trigonal pyramids. A full O/F anionic ordering is observed and the electro...

The interactions between chromium(III) and 3,4-dihydroxybenzoic acid (3,4-DHBA) were studied resulting in the formation of oxygen-bonded complexes upon substitution of water molecules in the chromium(III) coordination sphere. The experimental results show that the reaction takes place in at least three stages, involving various intermediates. The first stage was found to be linearly dependent o...

In the presented paper, the influence of the molecular weight and the type of polyamino acid functional groups on the electrokinetic properties and the stability of chromium (III) oxide suspension were examined. Analysis of the data obtained from the adsorption, potentiometric titration, zeta potential, and stability measurements allows to propose stabilization or destabilization mechanism of t...

The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa-hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)-N = 2.0726 (10) Å] and two fluoride [average Cr(III)-F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a ne...

in parts of desert regions in our country, groundwater is the only source of fresh water and due to geological formation, the concentration of hexavalent chromium in groundwater will reach beyond the allowed limits. furthermore, previous studies showed that hexavalent chromium is a cancerous substance for humans and toxic for other organisms. in this study the removal of hexavalent chromium fro...

Studies suggest that chromium deficiency is associated with elevated levels of fasting blood glucose, circulating insulin, cholesterol and triglycerides, and decreased proportion of lean body mass. However, data directly relating chromium levels to metabolic syndrome (MetS) risk are lacking. A total of 3,648 American adults from the Coronary Artery Risk Development in Young Adults (CARDIA) stud...

The total content of chromium in natural waters does not generally exceed several μg/l. Thus, it is obvious that various forms of chromium will occur at the levels of tenths or hundredths of μg/l. Their determination requires the application of a sufficiently sensitive method, but its specificity has an important role to play in the case of chemical individuals or selectivity in regard to speci...

In ecological risk assessment for chemical pollutants, it is important to quantify the concentrations of freely dissolved substances in aqueous samples for approximate characterization of the bioavailable fraction. Such measurements are important because the concentration and toxicity of a chemical in an organism’s body are linked to the bioavailable fraction and its chemical form within the su...