Investment castings (usually involving ceramic based shells) have traditionally been separated from the mould tree using an abrasive cutting operation. While material removal rates are relatively high, the process unfortunately suffers from poor accuracy control that often necessitates further finishing operations. Following an overview of key considerations in investment casting including tree...

Introduction: In recent years, attraction toward drinking bottled mineral water has increased. Therefore, chemical composition and safety of these waters considering trace elements and heavy metals should confirm the national or international standard limits. The aim of this study was to evaluate and comparison of the mineral and heavy metal composition of bottled waters in Bandar Abbas with Ir...

Ternary intermetallic A–B–C systems sometimes have unexpected behaviors. The present paper examines situations in which there is a tendency to simultaneously form the compounds ABx, ACx and BCx with the same crystal structure. This causes irregular shapes of the phase homogeneity domains and, from a structural point of view, a complete reversal of site occupancies for the B atom when crossing t...

Systemic toxicity associated with cobalt (Co) and chromium (Cr) containing metal hip alloy may result in neuropathy, cardiomyopathy, and hypothyroidism. However clinical management concerning chelating therapy is still debated in literature. Here are described two metal-on-metal hip-implanted patients in which N-acetyl-cysteine decreased elevated blood metal levels. A 67-year-old male who under...

UNLABELLED The interest in using titanium to fabricate removable partial denture (RPD) frameworks has increased, but there are few studies evaluating the effects of casting methods on clasp behavior. OBJECTIVE This study compared the occurrence of porosities and the retentive force of commercially pure titanium (CP Ti) and cobalt-chromium (Co-Cr) removable partial denture circumferential clas...

The segregation behavior of the bimetallic alloys PtPd and CoCr in the case of bare surfaces and in the presence of an oxygen ad-layer has been studied by means of first-principles modeling based on density-functional theory (DFT). For both systems, change of the dband filling due to charge transfer between the alloy components, resulting in a shift of the d-band center of surface atoms compare...

The group 6 metal mono-, bis- and tris-ferrocenylphosphine complexes [M(CO)5(PH2Fc)] (1a, M = Cr; 1b, M = Mo; 1c, M = W), cis-[M(CO)4(PH2Fc)2] (2a, M = Cr; 2b, M = Mo; 2c, M = W) and fac-[M(CO)3(PH2Fc)3] (3a, M = Cr; 3b, M = Mo; 3c, M = W) [Fc = Fe(η(5)-C5H4)(η(5)-C5H5)] were prepared and fully characterised. IR and NMR spectroscopy and single-crystal X-ray diffraction analysis indicate that Fc...