Multi-modal imaging is an emerging area that integrates multiple imaging modalities to simultaneously capture visual information over many spatial scales. Complementary contrast agents need to be co-developed in order to achieve high resolution and contrast. In this work, we demonstrated that rare-earth doped particles (REDPs) can be employed as dual-modal imaging agents for both luminescence a...

Mn4+-activated hexafluoroaluminates are promising red-emitting phosphors for white light emitting diodes (w-LEDs). Here, we report the synthesis of Na₃AlF₆:Mn4+, K₃AlF₆:Mn4+ and K₂NaAlF₆:Mn4+ phosphors through a simple two-step co-precipitation method. Highly monodisperse large (~20 μm) smoothed-octahedron shaped crystallites are obtained for K₂NaAlF₆:Mn4+. The large size, regular shape and sma...

Crystallisation of [Co(CN)(6)](3-) or [Cr(CN)(6)](3-) with Ln(iii) salts (Ln = Nd, Gd, Yb) from aqueous dmf afforded the cyanide-bridged d/f systems [Ln(dmf)(4)(H(2)O)(3)(micro-CN)Co(CN)(5)] (-, discrete dinuclear species) and {[Cr(CN)(4)(micro-CN)(2)Ln(H(2)O)(2)(dmf)(4)]}(infinity) (-, infinite cyanide-bridged chains with alternating Cr and Ln centres). With Ln = Gd the characteristic long-liv...

The optical properties of ~ r ~ ' doped LiNbO LiNb03(MgO) and 3' LiNbO (ZnO) have been studied. Polarized absorption and laser excited 3 luminescence spectra at liquid-He temperature show different structure dependent on the co-dopants (MgO, ZnO). The relationship between the optical characteristics and the impurity sites location is discussed. LiNb03 crystals doped with rare earth ions have be...

Developing new hosts is one of the significant and intriguing aspects in the field of luminescence materials. Herein, we report a novel LiInTi2O6 host for phosphors in solid state lighting. The sub-solidus phase relationships, thermal stability, crystal structure, as well as compositionand temperature-dependent luminescence were investigated and discussed by means of various analytical techniqu...

A new type of supramolecular chemosensor based on the polyoxometalate (POM) Na9DyW10O36 (DyW10) and the block copolymer poly(ethylene oxide-b-N,N-dimethylaminoethyl methacrylate) (PEO114-b-PDMAEMA16) is reported. By taking advantage of the CO2 sensitivity of PDMAEMA blocks to protonate the neutral tertiary amino groups, CO2 can induce the electrostatic coassembly of anionic DyW10 with protonate...

An understanding of the aggregates and properties of positional isomers can not only uncover how a slight difference in molecular structure alter crystal packing and bulk solid-state properties, but also plays an important role in developing new types of molecule-based functional materials. Herein, we report a study of the molecular packing and static/dynamic luminescence properties of three cy...

The time response behavior of Aanderaa optodes model 3830, 4330, and 4330F, as well as a Sea-Bird SBE63 optode and a JFE Alec Co. Rinko dissolved oxygen sensor was analyzed both in the laboratory and in the field. The main factor for the time response is the dynamic regime, i.e., the water flow around the sensor that influences the boundary layer’s dynamics. Response times can be drastically re...