A new form of nanoporous material, metal intercalated covalent organic framework (MCOF) is proposed and its energy storage property revealed. Employing density functional and thermodynamical analysis, we find that stable, chemically active, porous materials could form by stacking covalent organic framework (COF) layers with metals as a gluing agent. Metal acts as active sites, while its aggrega...

We investigate the size distribution of damage clusters in concrete under uniaxial tension loading conditions. Using the finite-element method, the concrete is modeled at the mesoscale by a random distribution of elastic spherical aggregates within an elastic mortar paste. The propagation and coalescence of damage zones are then simulated by means of dynamically inserted cohesive elements. Dyna...

The cohesive energy of condensed matter in strong magnetic fields is a fundamental quantity characterizing magnetized neutron star surfaces. The cohesive energy refers to the energy required to pull an atom out of the bulk condensed matter at zero pressure. Theoretical models of pulsar and magnetar magnetospheres depend on the cohesive properties of the surface matter in strong magnetic fields....

Cohesive elements are commonly used to describe crack propagation in heterogeneous materials with toughening mechanisms. This work aims provide a guideline on how these fracture parameters can be calibrated using notch opening displacements (NODs) measured via digital image correlation and force data from wedge splitting tests (WSTs). Weighted finite element model updating was applied calibrate...

Cohesive-zone models for interfaces incorporate both strength and energy parameters. Therefore, they provide a natural bridge between strength-based models and energy-based models for fracture, allowing delamination to be described by a single framework that covers a range of applications for which the strength or energy criteria alone might not be sufficient. In this paper, the relationships b...

A three-dimensional finite element method is developed to predict the critical conditions necessary to nucleate electromigration or stress induced voids in interconnects. Our approach is to model interfaces using a modified cohesive zone, which permits the interfaces to separate at a critical stress, and also accounts for mass transport along the interfaces. A simple boundary value problem is s...

Presented is a constitutive framework for modeling the dynamic response of polycrystalline microstructures, posed in a thermodynamically consistent manner and accounting for finite deformation, strain rate dependence of flow stress, thermal softening, thermal expansion, heat conduction, and thermoelastic coupling. Assumptions of linear and square-root dependencies, respectively, of the stored e...

when geotechnical engineers are faced with cohesive clayey soils, the engineering properties of those soils may need to be improved to make them suitable for construction. the aim of this paper is to study the effect of using lime, natural pozzolana or a combination of both on the geotechnical characteristics of two cohesive soils. lime or natural pozzolana were added to these soils at ranges o...