We report temperature-dependent acoustic and densimetric data on changes in volume, expansibility, and adiabatic compressibility accompanying the binding of 1-adamantanecarboxylic acid (AD) to beta-cyclodextrin (beta-CD). We interpret our volumetric results in terms of hydration. Based on our compressibility and expansibility data, we estimate that, at 25 degrees C, the binding of AD to beta-CD...

It is shown that, by letting wavenumbers and frequencies complex in Hirota’s bilinear method, new classes of exact solutions of soliton equations can be obtained systematically. They include not only singular or N -homoclinic solutions but also N -wavepacket solutions. PACS: 03.40.Kf, 47.35.+i

Deceleration of the regioselective cis/trans isomerization of all-trans-astaxanthin (ASTX) in the presence of Ca2+ was shown by HPLC analysis. The NMR and ITC analyses provided evidence for complexation of ASTX with Ca2+ in 1:2 stoichiometry via chelation at both carbonyl and hydroxyl groups. The rotation across torsion omega6 (C5-C6-C7-C8) upon complexation is consistent with the NOE between 7...

The conditional stability constants of metal–sulfide complexes were determined in pH 8 seawater at various salinities, by Ž . flow-analysis with detection by cathodic stripping voltammetry FA-CSV . Two methods were used. The first method was titration of the sulfide by metal with detection of the free sulfide by FA-CSV. The titrant metals were Ag, Cd, Co, 2q 2q 2q 2q 3q 3q Ž . Fe , Mn , Pb , Zn...

We report a one-step synthesis of the phosphine, PPh(2)(i)C(3)F(7) from commercially available precursors. The stereoelectronic properties of the phosphine were probed by coordination to transition metals. Mo(CO)(5)PPh(2)(i)C(3)F(7) was synthesised and the synthesis and structure of trans-PtCl(2)(PPh(2)(i)C(3)F(7))(2) are described. PPh(2)(i)C(3)F(7) was found to be a bulky electron-withdrawing...

We study numerically the binding of one semiflexible charged polymer onto an oppositely charged sphere. Using parameters appropriate for DNA-histone complexes, we find complete wrapping for intermediate salt concentrations only, in agreement with experiments. For high salt concentrations, a strongly discontinuous dewrapping occurs. For low salt concentrations, we find multiple conformational tr...

Host–guest complexation of dithienylethene photoswitches with cucurbit[8]uril leads to photoresponsive binding pairs picomolar affinity in water.