nano silica sulfuric acid as a solid acid, was described to be an effective catalyst for one-pot three-component reaction of kojic acid, aryl aldehydes and indoles for the preparation of 2-substituted aryl (indolyl) kojic acid derivatives. the catalyst was prepared by combination of chlorosulfonic acid to nano silica gel. the size of nanoparticles were observed with sem.all prepared compounds w...

highly active cu (ii) complex with 1,4-dihydroxy anthraquinone as a cheap and accessable ligand could be used as a catalyst for the preparation of structurally different propargylamines from a one-pot, three-component reaction of terminal alkynes, aldehydes, and secondary amines with high yields under solvent-free conditions. the 1,4-dihydroxy anthraquinone is a very efficient cu(ii) scavenger ...

3,3,6,6-tetramethyl-9-phenyl-3,4,6,7,9,10-hexahydroacridine-1,8-(2h,5h)-dione derivatives are synthesized by nano titanium dioxide as an efficient and reusable heterogeneous nano catalyst in a one pot multi component reaction. easy preparation and separation of catalyst, simply workup procedure, clean reaction and reusability of the catalyst up to 7 times without appreciable loss of its catalyt...

ZrP2O7 nanoparticles have been used as an efficient catalyst for the preparation of 2-aryl-5-methyl-2,3-dihydro-1H-3-pyrazolones by a simple one-pot four-component reaction of phenyl hydrazines, ethyl acetoacetate ,β-naphthol and benzaldehydes under microwave irradiation in good to excellent yields. When the reaction was carried out using ZrOCl2.8H2O, ZrO2 and ZrP2O7 NPs as the catalyst, the pr...

A protocol for the synthesis of 1,4-dihydropyridines (Hantzsch type-products) was developed by means of a three-component condensation of an aldehyde, a β-dicarbonyl compound, ammonium acetate and nano Al2O3/KF as catalyst. This reaction was carried out under different conditions including i) solvent-free ii) and reflux in different solvents. In all conditions, the desired products were obtaine...

This work described a simple and efficient synthesis of dialkyl 3-(alkylamino)-1-aryl-1H-pyrazole-4,5-dicarboxylates via a three component reaction between arylhydrazine, alkylisocyanid and dialkylacetylenedicarboxylates in the presence of phenylisocyanate and α-Fe2O3 nanoparticles. Eco friendly, solvent-free conditions, excellent yields, and short reaction times, inexpensive and readily availa...

we wish to report a mild and efficient one-pot three-component reaction of an aryl aldehyde, malononitrile and barbituric acid or 4-hydroxycoumarinfor the synthesis ofpyrano[2,3-d]pyrimidine and dihydropyrano[c]chromene derivatives in the presence of iron ore pellet as a natural and reusable catalyst under heterogeneous and green conditions. the present methodology offers several advantages suc...

a simple, green and efficient method for synthesis of 2,4,5-trisubstituted imidazoles is described via three-component cyclocondensation of benzil or benzoin, aldehyde and ammonium acetate by using the nano sio2-supported ferric hydrogen sulfate (fhs/sio2), as a catalyst, under solvent-free conditions. the nano sio2 support and catalyst were characterized by x-ray diffraction (xrd), transmissio...

let $pounds$ be the category of locally compact abelian groups and $a,cin pounds$. in this paper, we define component extensions of $a$ by $c$ and show that the set of all component extensions of $a$ by $c$ forms a subgroup of $ext(c,a)$ whenever $a$ is a connected group. we establish conditions under which the component extensions split and determine lca groups which are component projective. ...