Identifying Cu-exchanged zeolites able to activate C-H bonds and selectively convert methane to methanol is a challenge in the field of biomimetic heterogeneous catalysis. Recent experiments point to the importance of trinuclear [Cu3(μ-O)3]2+ complexes inside the micropores of mordenite (MOR) zeolite for selective oxo-functionalization of methane. The electronic structures of these species, nam...

A new W/S/Cu cluster, [Cu(3)WIS(4)(C(21)H(21)O(3)P)(3)]·C(3)H(7)NO, was formed by the reaction of ammonium tetra-thio-tungstate(VI), cuprous iodide and tris-(4-methoxy-phen-yl)phosphine in N,N-dimethyl-formamide. The title compound exhibits a heavily distorted cubane-like skeleton in which the average Cu-I, Cu-S and W-μ(3)-S distances are 2.934, 2.302 and 2.249 Å, respectively. The W atom exhib...

Hydrothermal reactions of mixed ligands 5-methoxyisophthalate (CH(3)O-H(2)ip) and dipyridyl with Cu(OAc)(2).2H(2)O afford five new coordination polymers, including {[Cu(CH(3)O-ip)(bpa)].H(2)O}(n) (1), [Cu(2)(CH(3)O-ip)(2)(bpa)(0.5)(H(2)O)](n) (2), [Cu(2)(CH(3)O-ip)(2)(bpp)(H(2)O)](n) (3), {[Cu(3)(CH(3)O-ip)(3)(bpp)(2)(H(2)O)].3H(2)O}(n) (4) and [Cu(4)(CH(3)O-ip)(3)(bpe)(OH)(2)](n) (5) (bpp = 1,...

the inter-tidal mangrove environment of mengkabong lagoon is important as it supports the local fishing activities, nursery grounds for many fish and shellfish species, and as well as being central for ecotourism activities. the study showed that in general, the physicochemical parameters (ph, salinity and electrical conductivity), granulometric fractions, organic matter, base cations (na, k, c...

sediment core samples can provide useful information about aquatic environment. sedimentation rate, climate changes and heavy metal concentration are among the most important studies that are carried out on sediment cores. in this study, a sediment core of 70cm with aim of metal concentration investigation is collected from central part of the zarivar lake in the vicinity of the marivan city in...

Resistance to copper (Cu) toxicity in the respiratory pathogen Streptococcus pneumoniae is regulated by the Cu-specific metallosensor CopY. CopY is structurally related to the antibiotic-resistance regulatory proteins MecI and BlaI from Staphylococcus aureus, but is otherwise poorly characterized. Here we employ a multi-pronged experimental strategy to define the Spn CopY coordination chemistry...