We report the synthesis of halido Os(II) p-cymene complexes bearing bidentate chelating phenylazobenzothiazole (AZBTZ) ligands. Unlike the analogous phenylazopyridine (AZPY) complexes, AZBTZ-NMe2 is capable of both N,N-coordination to Os(II) and cyclometalation to form N,C-coordinated species. N,C-Coordination occurs via an azo nitrogen and an ortho carbon on the aniline ring, as identified by ...

The antimetastatic ruthenium(II) compounds [Ru(η(6)-p-cymene)Cl(2)(PTA)] (PTA = 1,3,5-triaza-7-phosphaadamantane) (RAPTA-C) and [Ru(η(6)-toluene)Cl(2)(PTA)] (RAPTA-T), as well as their analogues [Ru(η(6)-p-cymene)Cl(2)(DAPTA)] (DAPTA = (3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)) (DAPTA-C) and [Ru(η(6)-toluene)Cl(2)(DAPTA)] (DAPTA-T), respectively, were tested in in vitro bioassay...

BACKGROUND The efficacy of essential oil of Chenopodium ambrosioides flowering aerial parts and its three main active ingredients was evaluated against Blattella germanica male adults. METHODS Composition of essential oil was determined by GC-MS. Topical application bioassay was used to evaluate contact toxicity of essential oil and three main components. Fumigant toxicity of essential oil an...

The intramolecular sp2 and sp3 C-H activated products, as well as the monometalated products, based on the "(p-cymene)Ru(NHC)" framework were synthesised by treatment of a series of NHCs (1-R-3-methylimidazol-2-ylidene [R=Ph (1), Bn (2), t-Bu (3), i-Pr (4), Mes (5), Cy (6)] and 1,3-bis(isopropyl)imidazol-2-ylidene (7)) with [(p-cymene)RuCl2]2 under mild conditions. A new NHC precursor (1-tert-b...

The essential oil from the aerial parts of Iranian and British Thymus vulgaris L. were obtained by hydro distillation and analyzed by gas chromatography (GC) and gas chromatographymass spectrometry (GC-MS). Forty two components were identified in the Iranian Th. vulgaris essential oil that represented 99.06% of the oils. The major components were thymol (60.54%), γTerpinene (9.47%), p-cymene (8...

We report on the synthesis of a variety of C,E-bidentate triazolylidene ruthenium complexes that comprise different donor substituents E (E = C: phenyl anion; E = O: carboxylate, alkoxide; E = N: pyridine at heterocyclic carbon or nitrogen). Introduction of these donor functionalities is greatly facilitated by the synthetic versatility of triazoles, and their facile preparation routes. Five dif...

Endoclita signifer is a major wood-boring pest of eucalyptus trees in China, and its third instar larvae can accurately find infest mixed-species forests, although it also feed on another 51 tree species the same planted area. A total 34 volatile compounds were identified from trunks, including non-infested infested trunks with single or multiple (more than three) larval entrance cover packets,...

Essential oils produced by plants, and their components, could be sources of new natural herbicidal compounds. Thirteen extracted from six wild Lamiaceae species (namely Clinopodium suaveolens (Sm.) Kuntze, Satureja montana L. subsp. montana, Thymbra capitata (L.) Cav., Salvia fruticosa Mill. thomasii (Lacaita) Brullo, Guglielmo, Pavone & Terrasi, cuneifolia Ten., Thymus spinulosus Ten.) So...

Abstract The protic ionic liquid pyridine hydrochloride is known to be a non-aqueous solvent for metal oxides, including rare-earth oxides. However, its application in extractive metallurgy and especially extraction has been so far limited by miscibility with the aqueous phase. In this paper, molten (165 °C) was used dissolve production scrap of Nd–Fe–B permanent magnets recover valuable metals...