نتایج جستجو برای: derivatization followed by reductive cleavage dfrc

تعداد نتایج: 7100166  

Journal: :Drug metabolism and disposition: the biological fate of chemicals 2011
Catherine D Tsalta Armina Madatian Ernest M Schubert Fangming Xia William M Hardesty Yanli Deng Jennifer L Seymour Peter D Gorycki

GSK977779 is a potent HM74a agonist evaluated for the treatment of dyslipidemia. The disposition and metabolism of [(14)C]GSK977779 (67.6 μmol/kg p.o.) was studied in male and female rats. The compound was well absorbed and its primary route of elimination was in the feces. Based on metabolite profiling of plasma extracts and urine and bile samples, it was demonstrated that GSK977779 was extens...

Journal: :The Journal of organic chemistry 2007
Tasneem A Siddiquee Julie M Lukesh Sergey Lindeman William A Donaldson

The cyclopropane containing betaine, rac-dysibetaine CPa, was prepared from (1-methoxycarbonylpentadienyl)-Fe(CO)2PPh3+ by nucleophilic addition of nitromethane anion followed by oxidatively induced reductive elimination.

Journal: :Organic & biomolecular chemistry 2014
Dhevalapally B Ramachary Kodambahalli S Shruthi

Functionalized chiral tetrahydroquinolines were synthesized through supramolecular organocatalysis using quinidine-NH-thiourea 3c/L-phenylalanine 4i followed by reductive amination from the simple substrates.

In the presence of magnesium and hexamethylphosphorictriamide, HMPT, trimethylchlorosilane, TMS-C1, reacts with cyanoepoxides to give related compounds. Ring cleavage at ? - position of cyanoepoxide, 1, followed by the addition of two trimethylsilyl groups leads to 2 then substitution of OSiMei by trimethylsilyl or H takes place to give ?, ? - bis (trimethylsilyl) nitrile or ? - trimethyls...

Journal: :Journal of the American Chemical Society 2007
Franziska Schoenebeck John A Murphy Sheng-ze Zhou Yoshitaka Uenoyama Yves Miclo Tell Tuttle

The sulfonyl group finds extensive applications in organic and medicinal chemistry both in sulfonamides, popular as robust protecting groups for amines,1 and in sulfones.2 Frequently, sulfones are introduced into synthetic schemes to assist particular transformations; further progress along the synthetic route can later require the removal of a sulfone group, and this can be achieved by reducti...

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