a highly selective, rapid and economical differential pulse polarographic method has been developed for the determination of trace amounts of cadmium and lead present together in various standard alloys and biological samples after adsorption of their 1-(2-pyridylazo)-2-naphthol complexes on microcrystalline naphthalene. cadmium and lead complexes are equantitatively adsorbed on microcrystallin...

A new spectrophotometric method for the determination of palladium with Pyrogallol Red is described. Its high sensitivity is dependent on the presence of micellar system of 1-carbethoxypentadecyltrimethylammonium bromide, which leads to the maximum colour formation in acid solutions (pH 5.5) in a shorter time interval than in the absence of tenside. The ternary pal­ ladium-dye-cation-active ten...

Plants are the most common bioindicatorsused in air quality biomonitoring studies because they are immobile and they have more sensitive to the most prevalent air pollutants than humans and animals. To identify the concentrations and sources of heavy metals in ornamental plants of Isfahan landscape, samples of leaves and soil around Pinuseldarica and Nerium oleander were collected at different ...

Chelation, electrochemical, antioxidant and cytoprotective properties of six phenolics - cynarin and caffeic, chlorogenic, ferulic, protocatechuic and rosmarinic acids were studied on the following models: (i) chelation of transition metals, (ii) quenching of the diphenylpicrylhydrazyl radical (DPPH), (iii) determination of half-wave potential, (iv) erythrocytes or mitochondrial membranes damag...

Handheld X-ray fluorescence spectrometry (HH-XRF) has been established as the gold standard method for in-situ elemental determination in metals and alloys in the last 10 years. More than 5,000 analyzers are sold yearly worldwide for scrap metals sorting and positive material identification (PMI). PMI is a quality assurance tool consisting of the identification of alloy grades in various indust...