This contribution contains a survey of basic literature dealing with arrays of microelectrodes with overlapping diffusion layers as prospective tools in contemporary electrochemistry. Photolithographic thin layer technology allows the fabrication of sensors of micrometric dimensions separated with a very small gap. This fact allows the diffusion layers of single microelectrodes to overlap as me...

Using numerical simulation of diffusion inside diffusive gradients in thin films (DGT) samplers, we show that the effect of lateral diffusion inside the sampler on the solute flux into the sampler is a nonlinear function of the diffusion layer thickness and the physical sampling window size. In contrast, earlier work concluded that this effect was constant irrespective of parameters of the samp...

Molecular dynamics simulations were carried out to investigate the diffusive behavior of aqueous uranium species in montmorillonite pores. Three uranium species (UO(2)(2+), UO(2)CO(3), UO(2)(CO(3))(2)(2-)) were confirmed in both the adsorbed and diffuse layers. UO(2)(CO(3))(3)(4-) was neglected in the subsequent analysis due to its scare occurrence. The species-based diffusion coefficients in m...

Equilibrium moisture contents (EMCs) and diffusion coefficients of a high pressure laminate (HPL) overlay, a wood particleboard (PB) substrate, and an HPL backer (BCK) were measured at different levels of relative humidity (RH). The EMCs as a function of RH were fitted to the Nelson's sorption isotherm. It was found that Nelson's model reproduced accurately the experimental data of these differ...

In the last 10 years, there have been a number of studies in modeling of the deposition processes in flowlines. Most of these models: (1) assume empirical or semi-empirical correlations to predict the pressure drop and temperature profile, (2) ignore the radial convection flow in the layer composed of the two-phase wax and oil (that is the gel layer), and (3) use Fick’s law to describe the diff...

Collective cell migration plays a substantial role in maintaining the cohesion of epithelial cell layers and in wound healing. A number of mathematical models of this process have been developed, all of which reduce to essentially a reaction-diffusion equation with diffusion and proliferation terms that depend on material assumptions about the cell layer. In this paper we extend a one-dimension...

We present a method for simulating crystal growth by energetic beam deposition. The method combines a kinetic Monte Carlo simulation for the thermal surface diffusion with a small scale molecular-dynamics simulation of every single deposition event. We have implemented the method using the effective medium theory as a model potential for the atomic interactions, and present simulations for Ag/A...