Palladium containing EMT zeolite catalyst (Pd/EMT) was prepared and used for the indirect oxidative carbonylation of methanol to dimethyl carbonate (DMC). The employed as a new support compared with conventional Pd FAU (Pd/FAU). Pd/EMT in contrast Pd/FAU exhibited high intrinsic activity turnover frequency 0.25 s−1 vs. 0.11 s−1. showed CO conversion 82% DMC selectivity 79%, that maintained at l...

The electrolyte is an important component of lithium-ion batteries, especially when it comes to cycling high-voltage cathode materials. In this paper, we propose algorithm for estimating both the oxidising and reducing potential electrolytes using molecular dynamics quantum chemistry techniques. This can help determine composition structure solvate complexes formed a salt dissolved in mixture s...

Aliphatic polycarbonates have attracted attention as degradable and sustainable materials contributing to the circular plastic economy. Their chemical recycling has not been sufficiently studied. In this study, efficacy of organocatalysts for depolymerization poly(trimethylene carbonate) (PTMC), a representative aliphatic polycarbonate, is investigated using several organic acids bases. The hyd...

The near-limit oscillatory behaviors on wick flames of dimethyl carbonate (DMC) with trimethyl phosphate (TMP) additions have been investigated experimentally. experiments were conducted under a burner in conjunction the limiting oxygen concentration test (wick-LOC), and fuels selected as typical examples electrolyte solvents organophosphorus compounds (OPCs) for lithium-ion batteries. oscillat...