During the last decades, replacement of traditionally petro-based raw materials by eco-friendly substances in polyurethane production has become a great challenge. The synthesis polyurethanes is mainly conducted means selective reaction between active isocyanate and hydroxyl groups, yielding characteristic segmented chemical structure. In this study, traditional solvent-based polycondensation f...

In this work, we present an efficient one-pot method for the synthesis of three new azo-isoxazoline derivatives (4a–c) from aromatic aldehydes, hydroxylamine hydrochloride and 4-(allyloxy)azobenzene. Thus, were synthesized via 1,3-dipolar cycloaddition using sodium dichloroisocyanurate (SDIC) as eco-friendly inexpensive oxidizing agent under ultrasound cavitation in water a green solvent. The d...

tetra-n-butyl ammonium hydroxide was used as a catalyst for one-pot, three component condensation reactions consisting of aromatic aldehydes, malononitrile and barbituric acid in ethanol:water solvent system at 60oc. current method has major advantages like mild reaction conditions with simple operation, high yields, by using a less toxic and lower costlier catalyst.in conclusion, we have explo...

in the current study, a magnetic inorganic–organic nanohybrid material (hpa/tpi-fe3o4) was produced and used as an efficient, highly recyclable and eco-friendly catalyst for the one-pot and multicomponent synthesis of 3,4-dihydroquinoxalin-2-amine, diazepine-tetrazole and benzodiazepine-2-carboxamide derivatives with high yields and in a short range of time (20–35 min). the nanohybrid catalyst ...

Since Sony launched the commercial lithium-ion cell in 1991, composition of liquid electrolytes has changed only slightly. The electrolyte consists highly flammable solvents and thus poses a safety risk. Solid-state ion conductors, classified as non-combustible safe, are being researched worldwide. However, they still have long way to go before available for cells. As an alternative, this study...

The current study emphasizes the process of synthesis of nanoparticles from the natural residue that is rapid and eco-friendly. So we present a simple and eco-friendly biosynthesis of silver nanoparticles using Ficus benghalensis fruit extract as reducing agent, rapid reduction of silver ions is observed leading to the formation of silver nanoparticles in solution. The synthesized nanoparticles...

ABSTRACT The functionalization of silica-coated Fe3O4 magnetic nanoparticles (Fe3O4@SiO2) using chlorosulfonic acid were afforded sulfonic acid-functionalized magnetic Fe3O4 nanoparticles (Fe3O4@SiO2-SO3H) that can be applied as an organic-inorganic hybrid heterogeneous catalyst. The used Fe3O4 magnetic nanoparticles are 18-30 nm sized that was rapidly functionalized and can be used as catalyst...

in this research, we have developed cheap recyclable and task-specific acidic ionic liquids (ails) 1-hydrogen-3-methylimidazolium hydrogen sulfate [hmim]hso4, 1-hydrogen-3-methylimidazolium chloride [hmim]cl, 2-pyrrolidonium hydrogensulfate [hnhp]hso4 and applied them in acid catalyzed synthesis of quinoxaline derivatives from 1,2-phenylendiamines and 1,2-dicarbonyl compounds. the products coul...

a simple and efficient method for the synthesis of quinolines and polycyclic quinolines using li+ modified nanoporous na+-montmorillonite is described. this new nanocatalyst proceeds via friedlander annulation under solvent-free conditions. it describes our observations about a trend of catalytic activity of lithium cation in nanoporous na+-montmorillonite. in this study, several types of 1,3-d...