The Fe/N/C catalysts have emerged recently as a representative class of non-Pt catalysts for oxygen electrocatalytic reduction, which could have a competitive catalytic performance to Pt. However, the nature of the catalyst remains elusive, especially on the active site structure and the electrocatalytic kinetics. Here we examine two kinds of Fe/N active sites for Fe/N/C catalysts, namely, the ...

The catalytic reduction of SO2 to elemental sulfur by CO or CH4 over ceria-based catalysts under demanding operating conditions is reported in this paper. Cuor Ni-containing ceria catalysts have been shown before to be highly active and selective for SO2 reduction by CO in dry gas streams or in the presence of low amounts of H2O. In this work, the activity/selectivity of 10 at.%La-doped ceria, ...

Proton exchangemembrane fuel cells are promising candidates for a clean and efficient energy conversion in the future, the development of carbon based inexpensive non-precious metal ORR catalyst has becoming one of the most attractive topics in fuel cell field. Herein we report a Feand Ndoped carbon catalyst Fe-PANI/C-Mela with graphene structure and the surface area up to 702 m g. In 0.1 MHClO...

In industry, one of the main catalysts typically employed for the selective oxidation of methanol to formaldehyde is a multi-component oxide containing both bulk Fe2(MoO4)3 and excess MoO3. It is thought that the excess MoO3 primarily acts to replace any molybdenum lost through sublimation at elevated temperatures, therefore preventing the formation of an unselective Fe2O3 phase. With both oxid...

Polycrystalline Fe-doped alumina (Al2O3) ceramics have been produced and used as a substrate for organized carbon nanotubes (CNTs) growth by catalytic chemical vapor deposition (CCVD). In these substrates, Fe cations, which are the catalyst source, are initially substituted to Al in a-Al2O3, instead of being simply deposited as a thin Fe layer on the surface of the substrate. The selective redu...

Scanning electron microscopy, and magnetization measurements reveal that as cast (Nd1 xCex)2Fe14B alloys contain significant amounts of a-Fe that can be dramatically reduced by annealing the alloys at 1000 C for 3 days. The room temperature intrinsic coercivity, Hci, of (Nd0.8Ce0.2)2.2Fe14B melt spun ribbons was found to be 11 kOe, which is ~32e~10% higher in comparison to that of Nd2Fe14B (Hci...

In the present work advanced oxidation process, photo-Fenton (UV/H2O2/Fe) system, for the treatment of wastewater contaminated with oil was investigated. The reaction was influenced by the input concentration of hydrogen peroxide H2O2, the initial amount of the iron catalyst Fe, pH, temperature and the concentration of oil in the wastewater. The removal efficiency for the system UV/ H2O2/Fe at ...

Abstract The gasification of biomass produces a syngas that can be used for electricity generation and fuels/chemicals production. However, tar is generated along with the as by-product which causes problematic issues in end-use syngas, such blockages, plugging corrosion. Catalytic steam reforming suitable option to convert into more presence nickel-based catalysts, preferred catalyst, mainly d...