Ionic liquids based on 1-alkyl-3-methylimidazolium cations and the hydrogen sulfate (or bisulfate) anion, HSO(4)(-), are much more viscous than ionic liquids with alkyl sulfates, RSO(4)(-). The structural origin of the high viscosity of HSO(4)(-) ionic liquids is unraveled from detailed comparison of the anion Raman bands in 1-ethyl-3-methylimidazolium hydrogen sulfate and 1-butyl-3-methylimida...

Introduction: Meridiani Planum was chosen as the landing site for the Mars Exploration Rover Opportunity partially based on Mars Global Surveyor Thermal Emission Spectrometer data indicating an abundance of hematite [1]. Hematite often forms through processes that involve water, so the site was a promising one to determine whether conditions on Mars were ever suitable for life [1,2]. Opportunit...

Aluminum sulfate (alum), ferrous sulfate, ferric chloride and ferric chloro-sulfate were commonly used as coagulants. However, a possible link of Alzheimer’s disease with conventional aluminium based coagulants has become an issue in wastewater treatment. Hence, special attention has shift towards using biodegradable polymer, chitosan in treatment, which are more environmental friendly. Moreove...

PO4(3-) and SiO3(2-) are often used as modifier to improve stability and aggregating ability of the iron-base coagulants, however, there are few reports about their detailed comparison between the coagulation performance and mechanisms. In this study, three coagulants--polyferric phosphoric sulfate (PFPS), polysilicon ferric sulfate (PFSS), and polyferric sulfate (PFS) were synthesized; their s...

Abstract: has been investigated. It has been shown that the mechanism of leaching reaction is diffusion through the product layerand does not undergo any change as a result of mechanical activation in a wide range of experimental conditions.Leaching rate is strongly influenced by milling intensity and the effect of ball to powder mass ratio is stronger thanmilling time. Curve fitting of experim...

The cations and anions of the title salt, 3C(6)H(16)N(+)·HSO(4) (-)·SO(4) (2-), are linked by N-H⋯O and O-H⋯O hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S-O(H) bond of 1.563 (2) Å, forms a short O-H⋯O hydrogen bond [O⋯O = 2.609 (2) Å] to the sulfate ion. The hydrogensulfate ion accepts two hydrogen bonds from two cations, whereas the sulfate ion, as ...

In this study, oxidation of some 3,5-diacyl or 3,5-diester 1,4-dihydropyridines to corresponding pyridine derivatives using sodium bromate in the presence of NH4Cl, NaHSO4 and Bu4NHSO4 under thermal conditions has been investigated. The yield and structure of formed products is similar under all conditions; however, the reaction is accelerated in the presence of Bu4NHSO4 and NaHSO4. In addition...