It is reported (J. B. S. Shear, C. Xu and W. W. Webb, Photochem. Photobiol. 1997, 65, 931) that multiphoton near infrared excitation of 5-hydroxytryptophan results in a transient product with green fluorescence. Visible fluorescence from multiphoton excitation enables detection of 5-hydroxytryptophan with extremely high sensitivity and also has potential applications in imaging of biological sy...

Binary solvent mixtures with a suitable polarity and viscosity profile are viable green alternatives to DMF in solid-phase peptide synthesis.

The reaction between diaminomaleonitrile (DAMN) and aldehydes and the resulting monoimines are well known. Since the standard reaction conditions involve the use of toxic solvents (typically methanol), we have sought to apply green chemistry principles to this reaction by either using water as the solvent without any catalysts or employing "solvent-free" conditions. The monoimines derived from ...

Chapter abstract: Subcritical water extraction (SWE) is presented in this chapter as a potent and novel alternative to conventional solvent extraction processes for isolating bioactive components from algae. SWE is defined as the extraction with water at temperatures ranging from the boiling point to the critical point and at pressures high enough to keep the water in the liquid state throughou...

A solvent-to-polymer upgrading strategy was developed to convert green solvents of the lactic acid portfolio into LCST-type acrylic polymers and hydrogels.

Cyclopentyl methyl ether (CPME) has been used in chemical synthesis as an alternative to hazardous solvents. According to some earlier investigation by others, CPME has low acute or subchronic toxicity with moderate irritation and negative mutagenicity and negative skin sensitization (Local Lymph Node Assay). Calculated Permitted Daily Exposure (PDE) value of CPME obtained by our 28-day oral to...

In this researchsaccharomyces cerevisiae (baker’s yeast) was used as a cheap, readily accessible, selective, efficient, and green bio-catalyst in a chemo selective reduction of carbonyl group to hydroxyl group. In this green procedure three substrates e.g. (3-(3-nitrophenyl)aziridin-2-yl)-1-phenyl-methanone, pyruvate ester, and 2-acetyl-γ-butyrolactone were r...

in this work, so3h-functionalizedphthalimide (sfp) as a so3h-containing solid acid is prepared by the reaction of phthalimide with chlorosulfonic acid, and characterized by ft-ir, 1h and 13c nmr, mass, tg, dtg, xrd and sem. then, it is utilized as a highly efficient, heterogeneous and green catalyst for the one-pot multi-component condensation of dimedone with arylaldehydes, β-ketoesters and am...

The effects of extraction solvents (hexane, ethyl-acetate, acetone, ethanol, methanol, and water) on the content of phytochemicals including total polyphenols, flavonoids and condensed tannins, as well as antioxidant activities of walnut green husk were investigated. The results showed that extraction solvents significantly affected phytochemicals content and antioxidant activities of walnut gr...