Crystal structures of racemic and homochiral forms of 2-phenylbutyramide (1) and 3-methyl-3-phenylpyrrolidine-2,5-dione (2) were investigated in detail by a single crystal X-ray diffraction study. Absolute configurations of the homochiral forms of 1 and 2, obtained by chromatographic separation of racemates, were determined. It was revealed that racemate and homochiral forms of 1 are very simil...

The purpose of this study was to synthesize biomaterials from daily dental waste. Since alginate impression material contains silica and calcium salts, we aimed to synthesize calcium silicate cement from alginate impression material. Gypsum-based investment material was also investigated as control. X-ray diffraction analyses revealed that although firing the set gypsum-based and modified inves...

Neutralization of Acidic Sulfur Species by Calcite in Mineral Aerosols Collected in China and Japan Studied by Ca K-Edge X-Ray Absorption Near-Edge Structure Spectroscopy X-ray absorption near-edge structure studies at the calcium K-edge have been used to show that acidic sulfur species in the atmosphere (e.g., H2SO4), mainly released by human activities, can be neutralized by the calcite prese...

A numerical analysis of the evolution with time of an abandoned gypsum mine flooded by water is presented. The lay-out of the problem is shown first, together with the experimental results obtained in laboratory tests on gypsum specimens retrieved from site. An elastic-plastic strain-hardening constitutive model, capable of taking weathering effects into account, is sketched next. A chemo-mecha...