Photocatalytic oxidation of the sulfur-containing compounds, trimethylene sulfide (C3H6S), propylene sulfide (C3H6S), thiophene (C4H4S), and methyl disulfide (C2H6S2), was carried out using an annular plug flow reactor with TiO2 in a supported form. Formation of products and byproducts was monitored in real time using a mass spectrometry online system. Mineralization of the sulfur-containing co...

Low-temperature (6)Li, (13)C, and (15)N NMR spectroscopies reveal that mixtures of n-BuLi and (1R,2S)-R'(2)NCH(R)CH(Ph)OLi (ROLi; R = Ph or Me; R'(2)N = pyrrolidino or Me(2)N) in THF/pentane afford a (n-BuLi)(3)(ROLi) (3:1) mixed tetramer and a C(2)-symmetric (n-BuLi)(2)(ROLi)(2) (2:2) mixed tetramer depending on the proportions of the reactants. The corresponding (n-BuLi)(ROLi)(3) (1:3) mixed ...

l'auteur explique le comportement des esters cycliques neutres vis -a- vis de l'eau ,de l'acide chlorhydrique , ainsi que la polymerisation des ethylphosphates cycliques d'ethylene et de propylene par des traces d'eau. les produits resultant de la plymerisation de ce dernicr phosphate cyclique sont plus complexes que ceux obtenus dans les memes conditions avec 1'et...

Many organic-rich rocks are major sources of oil and gas in sedimentary basins presumably through high-temperature thermal cracking. This view was brought into question with recent reports of marine shales generating catalytic gas in the laboratory at 50◦C, 300◦C below thermal-cracking temperatures. Gas forms under natural conditions without artificial stimulation. Compositions of methane, etha...

Propylene glycol (PG) is a solvent commonly used in medications that, while benign at low doses, may cause toxicity in adults and children at high doses. We describe a case and the physiologic sequelae of propylene glycol toxicity manifested in a critically ill adolescent male with refractory myoclonic status epilepticus aggressively treated with multiple PG-containing medications (lorazepam, p...

Vesicles formed in water by synthetic macro-amphiphiles have attracted much attention as nanocontainers having properties that extend the physical and chemical limits of liposomes. We sought to develop ABA block copolymeric amphiphiles that self-assemble into unilamellar vesicles that can be further oxidatively destabilized. We selected poly(ethylene glycol) (PEG) as the hydrophilic A blocks, o...

This study developed single-well, gas-sparging tests for assessing the feasibility of in situ aerobic cometabolism of trichloroethene (TCE) and cis-1,2-dichloroethene (cis-DCE) using propane and methane as growth substrates. Tests were performed in groundwater contaminated with TCE (100-400 microg l(-1)) and cis-DCE (20-60 microg l(-1)). A series of gas-sparging tests was performed by first spa...

Traditional systems for olefin/paraffin separation, like low-temperature distillation, are expensive and very energy consuming, and therefore, alternative separation methods are desired. Facilitated transport membranes are new tools for this separation to be substituted in large scale separation of olefin-paraffin mixtures. To design a membrane process for olefin-paraffin separation, equilibriu...