نتایج جستجو برای: interfacial activity

تعداد نتایج: 1155374  

Journal: :journal of chemical and petroleum engineering 2011
hozhabr sohbat zadeh hosein abolghasemi mohammad ghannadi maragheh amir khacpai

in this paper, we studied effect of different parameters including density, viscosity, interfacial tension and solute transfer concentration on phase inversion hold-up. the results showed that change in phase density ratio had no effect on phase inversion hold-up. it also disclosed that the phase viscosity ratio was the most effective parameter affecting phase inversion hold-up and each phase h...

2003
Scott A. Bradford Feike J. Leij

Knowledge of the fluid-fluid and fluid-solid interfacial areas is important to better understand and quantify many flow and transport processes in porous media. This paper presents estimates for interfacial areas of porous media containing two or three fluids from measured capillary pressure (PC)-saturation (S) relations. The thermodynamic treatment of two-fluid PC-S relations presented by Morr...

Journal: :Journal of molecular modeling 2017
R Catarino Centeno R A Bustamante-Rendón J S Hernández-Fragoso I Arroyo-Ordoñez E Pérez S J Alas A Gama Goicochea

The interfacial tension between immiscible liquids is studied as a function of a model linear surfactant length and concentration using coarse-grained, dissipative particle dynamics numerical simulations. The adsorption isotherms obtained from the simulations are found to be in agreement with Langmuir's model. The reduction of the interfacial tension with increasing surfactant concentration is ...

2015
Qiao-min Wang Bing Sun Zhi-yu Yan Xiao-mei Zhu Hui Liu Yan-bin Xin

The oil spill dispersant (OSD) play an important role to deal with the frequent oil spills in the marine environment, which can effectively reduce the interfacial tension between the oil and the seawater. However, there are many studies showing the stability of the OSD effect changes over time, and is related with the wave. In this paper, the results show the OSD will gradually move away from t...

Journal: :Nature materials 2015
Uwe Bauer Lide Yao Aik Jun Tan Parnika Agrawal Satoru Emori Harry L Tuller Sebastiaan van Dijken Geoffrey S D Beach

In metal/oxide heterostructures, rich chemical, electronic, magnetic and mechanical properties can emerge from interfacial chemistry and structure. The possibility to dynamically control interface characteristics with an electric field paves the way towards voltage control of these properties in solid-state devices. Here, we show that electrical switching of the interfacial oxidation state allo...

Journal: :Physical review. E, Statistical, nonlinear, and soft matter physics 2002
Richard P Sear

Mixtures of ideal polymers with hard spheres whose diameters are smaller than the radius of gyration of the polymer, exhibit extensive immiscibility. The interfacial tension between demixed phases of these mixtures is estimated, as is the barrier to nucleation. The barrier is found to scale linearly with the radius of the polymer, causing it to become large for large polymers. Thus for large po...

Journal: :The Journal of chemical physics 2015
Gabriel V Lau Ian J Ford Patricia A Hunt Erich A Müller George Jackson

The test-area (TA) perturbation approach has been gaining popularity as a methodology for the direct computation of the interfacial tension in molecular simulation. Though originally implemented for planar interfaces, the TA approach has also been used to analyze the interfacial properties of curved liquid interfaces. Here, we provide an interpretation of the TA method taking the view that it c...

Journal: :Langmuir : the ACS journal of surfaces and colloids 2014
Aditi Chakrabarti Manoj K Chaudhury

We study the interaction of small hydrophobic particles on the surface of an ultrasoft elastic gel, in which a small amount of elasticity of the medium balances the weights of the particles. The excess energy of the surface of the deformed gel causes them to attract as is the case with the generic capillary interactions of particles on a liquid surface. The variation of the gravitational potent...

2017
Amit Kumar Bhattacharjee

For isotropic fluids, classical nucleation theory predicts the nucleation rate, barrier height and critical droplet size by ac- counting for the competition between bulk energy and interfacial tension. The nucleation process in liquid crystals is less understood. We numerically investigate nucleation in monolayered nematogenic films using a mesoscopic framework, in par- ticular, we study the mo...

Journal: :The Journal of chemical physics 2005
Kostya Shundyak René van Roij Paul van der Schoot

Within a second virial theory, we study bulk phase diagrams as well as the free planar isotropic-nematic interface of binary mixtures of nonadditive thin and thick hard rods. For species of the same type, the excluded volume is determined only by the dimensions of the particles, whereas for dissimilar ones it is taken to be larger or smaller than that, giving rise to a nonadditivity that can be...

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