An unprecedented family of novel electron-donor acceptor conjugates based on fullerenes as electron acceptors, on one hand, and triphenyl amines as electron donors, on the other hand, have been synthesized and characterized in a variety of solvents using steady state absorption/emission as well as transient absorption spectroscopy. These are unprecedented in terms of their outcome of radical io...

Methods for separation of ions by ion-exchange, ion-pair, and zwitterion ion chromatography share at least one common thread--the induced formation of a cation-anion pair in the stationary phase. Selectivity can be defined as the relative ability of sample ions to form such a pair. Examples are given in anion-exchange chromatography to show the effect of variations in the geometry, bulkiness an...

The mechanism of hydrolysis of the nitrile (N-acetyl-phenylalanyl-2-amino-propionitrile, I) catalyzed by Gln19Glu mutant of papain has been studied by nanosecond molecular dynamics (MD) simulations. MD simulations of the complex of mutant enzyme with I and of mutant enzyme covalently attached to both neutral (II) and protonated (III) thioimidate intermediates were performed. An MD simulation wi...

the main factor affecting the economics of foam-assisted water alternative gas (fawag) process isthe loss of foaming agent by adsorption onto reservoir rocks. in this study, the effects of phases,surfactant concentration, salinity, adsorbents, and sacrificial agent on adsorption density wereinvestigated by special adsorption experiments. moreover, a series of fawag tests were performedto examin...

Upon charge transfer (Os to carbyne) excitation the carbyne complexes Os(CPh)(CO)(PPh3)2Cl and [Os(CPh)(CO)2(PPh3)2]+ with Ph = C6H5 are converted to the carbene complex Os(CHPh)(CO)(PPh3)2Cl2 in solutions containing HCl. It is suggested that the relaxed CT state can be described as square-pyramidal Os(II) complex containing a bent carbyne ligand which carries a lone pair at the coordinating ca...

Citation: Waska H, Koschinsky A and Dittmar T (2016) Feand Cu-Complex Formation with Artificial Ligands Investigated by Ultra-High Resolution Fourier-Transform ion Cyclotron Resonance Mass Spectrometry (FT-ICR-MS): Implications for Natural Metal-Organic Complex Studies. Front. Mar. Sci. 3:119. doi: 10.3389/fmars.2016.00119 Feand Cu-Complex Formation with Artificial Ligands Investigated by Ultra...

The objective of this study was to examine the effect of ion-pair complexation with endogenous bile salts on the transport of a quarternary ammonium organic cationic (OC) drug, berberine, across the Caco-2 and LLC-PK1 cell monolayers. The basolateral-to-apical (BL-AP) transport of berberine in Caco-2 cells was temperature dependent and 10-fold higher than that of the apical-to-basolateral (AP-B...