Nanotubes can selectively conduct ions across membranes to make ionic devices with transport characteristics similar to biological ion channels and semiconductor electron devices. Depending on the surface charge profile of the nanopore, ohmic resistors, rectifiers, and diodes can be made. Here we show that a uniformly charged conical nanopore can have all these transport properties by changing ...

Vesicular glutamate transporters (VGLUTs) accumulate the neurotransmitter glutamate in synaptic vesicles. Transport depends on a V-ATPase-dependent electrochemical proton gradient (ΔμH+) and requires chloride ions, but how chloride acts and how ionic and charge balance is maintained during transport is controversial. Using a reconstitution approach, we used an exogenous proton pump to drive VGL...

Polymer-electrolyte membranes (PEMs) are a key component in electrochemical energy conversion devices where their main function is to selectively transport ionic species. Reducing PEM thickness an effective strategy for improving performance by minimizing losses. However, how affects the intrinsic properties of membrane remains unexplored. This work aims understand effect on structure-property ...

This paper explores the role and biophysical expression of the equivalent electrical circuit model as it applies to ionic conductances across the paracellular shunt, apical membrane, and basolateral membrane of the Ambystoma renal proximal tubule. Information about such conductances may be experimentally determined through transepithelial voltage and intracellular voltage measurements. The equi...

A series of 'dual-functionalised' ionic liquids, comprising imidazolium cations with various functionalities and the nitrile functionalised anion [CH3CH(BF3)CH2CN]- have been prepared; some exhibit very low viscosities-a highly valuable property in many applications.

Recently, in addition to the well-known resistor, capacitor, and inductor, a fourth passive circuit element, named memristor, has been identified following theoretical predictions. The model example used in such case consisted in a nanoscale system with coupled ionic and electronic transport. Here, we discuss a system whose memristive behavior is based entirely on the electron-spin degree of fr...

A tight [2]rotaxane with two chromophores as stoppers is described, in which the macrocycle is able to reversibly move by tuning of base. This moving process can result in intramolecular photo-induced electron transfer (PET), changing the photo-physical properties.

Common analysis (level 1) characterizes the degree of ion association in polymer electrolytes by the Nernst-Einstein deviation parameter ∆ which quantifies the relative difference between the true ionic conductivity directly measured by electrical methods and the hypothetical maximum conductivity calculated from the individual ionic self-diffusion coefficients. Alternatively, the Haven ratio HR...

Decreasing the dimensions of ionic conductors to the nanoscale has enabled the realization of new electrochemical devices integrated on Si-based and other microsystems. These comprise fast ionic conducting electrolytes for energy-applications such as micro-fuel cells [ 1,2 ] and batteries, [ 3 ] gas conversion/reformation catalysts, [ 4,5 ] sensors, [ 6 ] and for redox-reaction based resistive ...

Ionmobility and ionic conductance in nanodevices are known todeviate frombulk behavior, a phenomenon often attributed to surface effects. We demonstrate that dielectric mismatch between the electrolyte and the surface can qualitatively alter ionic transport in a counterintuitive manner. Instead of following the polarization-induced modulation of the concentration profile, mobility is enhanced o...