The internal flow circulation dynamics of a liquid drop moving in a co- or counter-flowing gas stream has been numerically studied. The present work is concerned with the time accurate numerical solution of the two phase flow field at the low Mach number limit with an appropriate volume tracking method to capture motion and deformation of a liquid drop. It is shown that relative velocity betwee...

Atomic force microscopy (AFM), neutron reflection (NR) and secondary ion mass spectroscopy (SIMS) are used to examine phase separation in symmetrically segregating thin polymer blend films (e1000 Å). Phase separation in the film leads to undulations of the liquid-air interface, provided the film is sufficiently thin to suppress surface-directed spinodal decomposition waves. Flattened droplets a...

We developed a liquid crystal LC alignment method using a molecular template of an imprinted polymer layer during polymerization-induced phase separation. Our results showed that the nematic ordering of LC is transferred to the polymer chain ordering during an anisotropic phase separation, which produces an anisotropic azimuthal surface anchoring. Using in-plane field treatment during phase sep...

A relativistic meaneld model of nuclear matter with arbitrary proton fraction is studied at nite temperature. An analysis is performed of the liquid{ gas phase transition in a system with two conserved charges (baryon number and isospin) using the stability conditions on the free energy, the conservation laws, and Gibbs' criteria for phase equilibrium. For a binary system with two phases, the c...

This paper discusses the development of an invariant finite difference scheme to simulate the microphase separation of copolymers in one-dimensional thin liquid films. The film phenomena are modelled using two-phase shallow water equations and the Ohta–Kawasaki potential, which governs the phase separation of the copolymer. Non-positive volume fractions and spurious oscillations are eventually ...

We report the observation of liquid-liquid phase separation in a solution of human monoclonal antibody, IgG2, and the effects of human serum albumin, a major blood protein, on this phase separation. We find a significant reduction of phase separation temperature in the presence of albumin, and a preferential partitioning of the albumin into the antibody-rich phase. We provide a general thermody...

1 BACKGROUND Countercurrent chromatography (CCC) is liquid-liquid partition chromatography without using a solid support matrix. This technique requires further improvement of partition efficiency and shortening theseparation time. 2 METHODS The locular multilayer coils modified with and without mixer glass beads were developed for the separation of proteins and 4-methylumbelliferyl (MU) suga...

The effect of temperature on the phase behavior of a polycation-anionic/nonionic mixed micelle system, poly(dimethyldiallylammonium chloride)-sodium dodecylsulfate/Triton X-100, was studied over a wide range of surfactant compositions, ionic strengths, and polycation molecular weights using turbidimetry and dynamic light scattering. Soluble complexes become biphasic upon heating through either ...

Partially phase-separated liquid-crystal/polymer dispersions display highly fibrillar domain morphologies that are dramatically different from the typical structures found in isotropic mixtures. To explain this, we numerically explore the coupling between phase ordering and phase-separation kinetics in model two-dimensional fluid mixtures phase separating into a nematic phase, rich in liquid cr...

Liquid condensates are membraneless organelles that form via phase separation in living cells. These provide unique heterogeneous environments have much potential regulating a range of biochemical processes from gene expression to filamentous protein aggregation---a process linked Alzheimer's and Parkinson's diseases. Here we theoretically study the physical interplay between aggregation, its i...