نتایج جستجو برای: liquids

تعداد نتایج: 21511  

2015
Tomohiko Ooigawa

The present research tests Japanese listeners’ perception of Italian liquids under the framework of the Perceptual Assimilation Model (PAM), a model of non-native speech perception. The study examines the discrimination and the identification of Italian liquids (/l/, /r/, /ll/, /rr/ and /ʎ/), while comparing the results with those of replicated perception experiments of Spanish liquids (/l/, /ɾ...

Journal: :Physical review. E, Statistical, nonlinear, and soft matter physics 2009
Shuhei Fujimoto Yasushi Takeda

We report a deformation phenomenon occurring at the interface between two immiscible liquids. The two liquids are in a cylindrical container and set into motion by a rotating lid positioned above the interface. The upper liquid is more viscous than the lower and the difference in densities between the liquids is fairly small. As the rotational speed of the lid (Omega) is increased in small incr...

Journal: :Physical chemistry chemical physics : PCCP 2009
Koichi Fumino Alexander Wulf Ralf Ludwig

Cohesion energies determine the phase behavior of materials. The understanding of interaction energies is in particular interesting for ionic liquids. Here we show experimentally that, in accord with theoretical work, the intermolecular cation-anion interactions in ionic liquids can be detected by far FTIR spectroscopy. The measured vibrational bands of aprotic and protic ionic liquids in the l...

Journal: :Ultrasonics sonochemistry 2010
Meifang Zhou Thomas Seak Hou Leong Sonia Melino Francesca Cavalieri Sandra Kentish Muthupandian Ashokkumar

Liquid-encapsulated lysozyme microspheres were successfully synthesized using a sonochemical method. The encapsulation of four different liquids, namely, sunflower oil, tetradecane, dodecane and perfluorohexane on the formation, stability and morphology of the lysozyme microspheres was studied. Among the four different liquids used for encapsulation, perfluorohexane-filled microspheres were fou...

2013
Levon L Khemchyan Elena A Khokhlova Marina M Seitkalieva Valentine P Ananikov

An easy and convenient procedure is described for monitoring chemical reactions and characterization of compounds dissolved in ionic liquids using the well-known tandem mass spectrometry (MS/MS) technique. Generation of wastes was avoided by utilizing an easy procedure for analysis of ionic liquid systems without preliminary isolation and purification. The described procedure also decreased the...

2013
Markus Holzweber Ralf Lungwitz Denise Doerfler Stefan Spange Mihkel Koel Herbert Hutter Wolfgang Linert

Solute properties are known to be strongly influenced by solvent molecules due to solvation. This is due to mutual interaction as both the properties of the solute and of the solvent strongly depend on each other. The present paper is based on the idea that ionic liquids are cations solvated by anions and anions solvated by cations. To show this (in this system strongly pronounced) interaction ...

2011
Ditte Gundermann Ulf R. Pedersen Tina Hecksher Nicholas P. Bailey Bo Jakobsen Tage Christensen Niels B. Olsen Thomas B. Schrøder Daniel Fragiadakis Riccardo Casalini C. Michael Roland Jeppe C. Dyre Kristine Niss

Understanding the origin of the dramatic temperature and density dependence of the relaxation time of glass-forming liquids is a fundamental challenge in glass science. The recently established “density-scaling” relation quantifies the relative importance of temperature and density for the relaxation time in terms of a material-dependent exponent. We show that this exponent for approximate sing...

2016
Marta Falkowska Daniel T Bowron Haresh G Manyar Christopher Hardacre Tristan G A Youngs

Organic solvents, such as cyclohexane, cyclohexene, methylcyclohexane, benzene and toluene, are widely used as both reagents and solvents in industrial processes. Despite the ubiquity of these liquids, the local structures that govern the chemical properties have not been studied extensively. Herein, we report neutron diffraction measurements on liquid cyclohexane, cyclohexene, methylcyclohexan...

2009
Aleš Boškin Mladen Franko

Effects of selected ionic liquids on the efficiency of CPO oxidation of methyl-parathion were studied. In general, the activity of CPO decreases with the increased concentration of ionic liquid. For ionic liquids with the same cation, those with PF6 exhibit strongest inhibition toward CPO, while those with either BF4 or metSO4 show relatively lesser inhibition. It was further demonstrated that ...

Journal: :Physical review letters 2015
Marco Heinen Simon K Schnyder John F Brady Hartmut Löwen

We introduce fractal liquids by generalizing classical liquids of integer dimensions d=1,2,3 to a noninteger dimension dl. The particles composing the liquid are fractal objects and their configuration space is also fractal, with the same dimension. Realizations of our generic model system include microphase separated binary liquids in porous media, and highly branched liquid droplets confined ...

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