نتایج جستجو برای: mesopore

تعداد نتایج: 405  

Journal: :Water 2023

Soil–bentonite cut-off walls have been widely used to control landfill pollution but they do not good chemical compatibility with leachate. Attapulgite can be substituted for bentonite in walls. However, little is known about the of attapulgite and This study experimentally investigated wall specimens organic inorganic contaminants found that a sand–attapulgite has contaminants. A CaCl2 solutio...

Journal: :Physical chemistry chemical physics : PCCP 2013
Qian Huang Daiwon Choi Lelia Cosimbescu John P Lemmon

An organic radical based composite cathode comprised of poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA)-Ketjenblack was developed by a simple solvent-less electrode fabrication method. The composite cathode demonstrated a two-electron redox reaction of PTMA that is from an aminoxy anion (n-type) via a radical to an oxoammonium cation (p-type) with the corresponding redox potent...

Journal: :Sustainability 2023

The adsorption mechanism of carbon dioxide, oxygen and nitrogen in coal is important for preventing controlling spontaneous combustion understanding the technology CO2 storage goaf. Adsorption amount heat are key parameters that required to understand material energy conversions during coal. In this study, we studied factors influence amounts values by testing four different samples using conve...

Journal: :Applied sciences 2021

The effect of chemical activators on the properties activated carbon from sago waste was conducted in this study by using ZnCl2, H3PO4, KOH, and KMnO4 solutions. carbonized added to each solution, boiled at 85 °C for 4 h, heated 600 3 h. porosity, microstructural, proximate, surface chemistry analyses were carried out nitrogen adsorption with employing Brunauer Emmett Teller (BET) method Barret...

2017
Homer C Genuino Shanmugam Thiyagarajan Jan C van der Waal Ed de Jong Jacco van Haveren Daan S van Es Bert M Weckhuysen Pieter C A Bruijnincx

Bio-based furanics can be aromatized efficiently by sequential Diels-Alder (DA) addition and hydrogenation steps followed by tandem catalytic aromatization. With a combination of zeolite H-Y and Pd/C, the hydrogenated DA adduct of 2-methylfuran and maleic anhydride can thus be aromatized in the liquid phase and, to a certain extent, decarboxylated to give high yields of the aromatic products 3-...

Journal: :Journal of the American Chemical Society 2011
Zhuoying Xie Eric J Henderson Ömer Dag Wendong Wang Jennifer E Lofgreen Christian Kübel Torsten Scherer Peter M Brodersen Zhong-Ze Gu Geoffrey A Ozin

There has always been a fascination with "impossible" compounds, ones that do not break any rules of chemical bonding or valence but whose structures are unstable and do not exist. This instability can usually be rationalized in terms of chemical or physical restrictions associated with valence electron shells, multiple bonding, oxidation states, catenation, and the inert pair effect. In the pu...

Journal: :Chemistry 2012
Keiichi Miyasaka Hiroko Hano Yoshiki Kubota Yangzheng Lin Ryong Ryoo Masaki Takata Susumu Kitagawa Alexander V Neimark Osamu Terasaki

We present a modeling scheme to analyze cagelike silica mesoporous crystals based on in situ X-ray diffraction (XRD) data collected during gas adsorption-desorption (physisorption) processes. Nitrogen physisorption on a silica mesoporous crystal of SBA-16 was directly monitored by using synchrotron in situ powder XRD measurements conducted at SPring-8. SBA-16 is a well-ordered mesoporous silica...

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