Ultrasonic Waves, Carbon Dioxide, Nitrous Oxide, Methane, Free Radicals Water was irradiated with ultrasonic waves under an argon atmosphere which contained small amounts of carbon dioxide, nitrous oxide or methane. The yield of the products was measured as a function of the composition of the gas atmosphere. Maximum yields were observed at a few per cent of the added polyatomic gas. No chemica...

Sustainable development is the projected demand of all nations at present. Only 20 percent of world’s primary energy requirement is met by renewable sources like solar and wind energy, hydropower, biomass, municipal and agri-wastes. Especially energy recovery from municipal and agri – wastes have gained importance due to two – fold reason: i. waste volume reduction, ii. energy recovery. The pre...

Changes in fermenter gas composition within a given 24h period can cause severe bias in calculations of biogas or energy yields based on just one or two measurements of gas composition per day, as is common in other studies of two-stage fermentation. To overcome this bias, real time recording of gas composition and production were used to undertake a detailed and controlled comparison of single...

In this study, the co-digestion of cassava pulp (CP) and pig manure (PM) in a two-phase continuously stirred tank reactor (CSTR) was examined to find the optimum CP-to-PM mixture ratio (w/w volatile solids; VS) and to evaluate the effect of phase separation on the efficiencies of solid destruction and methane production. The results showed that the highest VS removal (29%) and the greatest prod...

Tannins, polyphenolic compounds found in plants, are known to complex with proteins of feed and rumen bacteria. This group of substances has the potential to reduce methane production either with or without negative effects on digestibility and microbial yield. In the first step of this study, 10 tannin-rich extracts from chestnut, mimosa, myrabolan, quebracho, sumach, tara, valonea, oak, cocoa...

Adding Cu to Ni/Al 2 O 3 is an excellent strategy suppress methane formation and enhance carbon monoxide yield through of alloyed nanoparticles.

Steam methane reforming is a major method of hydrogen production. However, this usually suffers from low energy efficiency and high carbon-emission intensity. To solve issue, novel steam-methane-reforming process over Ni-based catalyst in pressurized dual fluidized bed reactor proposed work. A three-dimensional computational fluid dynamics (CFD) model for the complex physicochemical was built t...

Tetramethylsilane reacts with 2,2,2-trifluoroethanol (TFE) in the presence of a cationic platinum(II) catalyst [(NN)PtMe(TFE)]+ (NN = 1,2-bis(3,5-dimethylphenylimino)butane). Catalytic Si-C bond heterolysis results in the formation of the trimethylsilyl ether, Me3SiOCH2CF3, accompanied by liberation of one equivalent of methane. Preliminary experiments suggest that a rate-determining C-H bond a...

Reaction of tris(5-amino-2-ethoxy-3-isopropylphenyl)methane and pyridine-2,6-dicarbonyl-dichloride affords a multi-dentate cryptand in 48% yield. Metallation with iron(III) chloride results in a substantial conformational change of this ligand to give a trianionic triiron(III) complex. Ferric cations line the periphery of the internal cavity with each adopting a square pyramidal N(3)Cl(2) coord...