The synthesis and characterization of the first Cr(V) complexes with non-sulfur-containing peptides, which may mimic the chemistry of the intermediates in the formation of Cr-induced peptide-DNA cross-links in vivo, are reported. The reduction of Cr(VI) with methanol in the presence of a number of non-sulfur-containing peptides produced relatively stable Cr(V)-peptide complexes, which were char...

We report the fabrication of transmission electron microscopy (TEM) grids bearing graphene oxide (GO) sheets that have been modified with Nα, Nα-dicarboxymethyllysine (NTA) and deactivating agents to block non-selective binding between GO-NTA sheets and non-target proteins. The resulting GO-NTA-coated grids with these improved antifouling properties were then used to isolate His6-T7 bacteriopha...

In 1959, the regional government of Western Nigeria established the 1st television station in Nigeria and in Africa. Even though it promoted the station as a means to educate the people about development and the world, it initially served as a means for an opposition leader to address the people of Western Nigeria. The regional governments of Eastern and Northern Nigeria and the federal gover...

The log K(1) value of analytical quality was obtained for the NiNTPA complex using the density functional theory (DFT)-computed (at the B3LYP/6-311++G(d,p) level of theory in solvent, CPCM/UAKS) G(aq) values of the lowest-energy conformers of the ligands, nitrilotriacetic acid (NTA) and nitrilotri-3-propanoic acid (NTPA), and the Ni(II) complexes (NiNTA and NiNTPA). The described mathematical p...

A new analytical system is described which provides total particle count and high-resolution size measurements for biological structures such as virus and protein aggregates. This system builds on the Nanoparticle Tracking and Analysis (NTA) technique for the simultaneous visualization and individual sizing of nanoparticles based on their Brownian motion. Virus production and purification proce...

Task-irrelevant stimulus numbers can automatically modulate concurrent temporal tasks--leading to the phenomenon of number-time association (NTA). Recent research provides converging evidence that the NTA occurs at the stage of temporal memory. Specifically, a reference memory containing encoded duration information can be modified by perceptual/concurrent digits, i.e., a perceptual/concurrent ...

Protonated a(2) and a(3) (therefore doubly charged) ions in which both charges lie on the peptide backbone are formed in collision-induced dissociations of [La(III)(peptide)(CH(3)CN)(m)](3+) complexes. Abundant (a(3)+H)(2+) ions are formed from triproline (PPP) and peptides with a proline residue at the N-terminus; these peptides are the most effective in producing ions of the type (a(2)+H)(2+)...

The electroanalytical technique Absence of Gradients and Nernstian Equilibrium Stripping (AGNES) has been extended by applying stripping chronopotentiometry (SCP) as the re-oxidation stage in the determination of the free concentration of Zn(2+), Cd(2+) and Pb(2+). This new approach, called AGNES-SCP, has been implemented with screen-printed electrodes (SPE) and the standard Hanging Mercury Dro...

The Langmuir-Schaefer (LS) method has been investigated as a means to control the structure of hybrid organoclay thin films consisting of montmorillonite and dimethyldioctadecylammonium (DODA) cations. We observed a significant modification of the compression isotherms as a function of clay mineral concentration in the subphase, implying clay interaction with the alkylammonium monolayer. For a ...

Relativistic density functional calculations were applied to study the separation behaviors of the Am(iii) ion from the Eu(iii) ion by diglycolamide (DGA) and nitrilotriacetamide (NTA) ligands in order to understand the difference in the separation mechanism of their reagents. The complexation reaction was modeled on the basis of previous experimental studies. The calculated energies based on s...