Vapor–liquid interfacial tension of square-well ~SW! fluids is calculated using three different methods viz., molecular dynamics ~MD! with collision-based virial evaluation, Monte Carlo with virial computed by volume perturbation, and Binder’s density-distribution method in conjunction with grand-canonical transition-matrix Monte Carlo ~GC-TMMC!. Three values of the SW attractive well range par...

The phase equilibria of non-conformal square-well monomer–dimer systems are examined using Gibbs ensemble Monte Carlo simulation and compared with results from the statistical associating fluid theory for potentials of variable attractive Ž . range SAFT-VR . For the first system of interest the square-well segments are of equal diameter and well-depth, the monomer has an attractive range of l s...

In a recent paper we predicted the fluid-phase equilibria of n-butane + n-alkane binary mixtures using the statistical associating fluid theory for chain molecules with attractive potentials of variable range (SAFTVR). Now we focus on the methane + n-hexane system, again using the SAFT-VR approach. The methane + n-hexane system exhibits type V phase behavior, in which partial miscibility of the...

Classical and nonclassical calculations of nucleation rates are presented for methanol, an associating vapor system. The calculations use an equation of state (EOS) that accounts for the effects of molecular association based on the statistical association fluid theory (SAFT). Two forms of classical nucleation theory (CNT) were studied: a Gibbsian form known as the P-form and the standard or S-...

Measurement of tris(hydroxymethyl)aminomethane buffers and blood samples was used to compare the following commercial pH instruments: Corning Models 160 and 165, Instrumentation Laboratory, Inc. Model 313, and Radiometer Models E5021 and BMS 3MK2. These comparisons uncovered a systematic bias of 0.02 pH units in Instrumentation Laboratory, Inc. electrodes manufactured before April 1973. Other f...

introduction: purkinje cell (pc) output displays a complex firing pattern consisting of high frequency sodium spikes and low frequency calcium spikes, and disruption in this firing behavior may contribute to cerebellar ataxia. riluzole, neuroprotective agent, has been demonstrated to have neuroprotective effects in cerebellar ataxia. here, the spectral analysis of pcs firing in control, 3-acety...