Synthesis of 2,5-bis(hydroxymethyl)furan (BHMF) by selective 5-hydroxymethylfurfural (HMF) hydrogenation is ecofriendly and industrially important since HMF obtained from renewable sources, BHMF a raw material used for production biodegradable polymers. Four copper-based catalysts were prepared incipient wetness impregnation (Cu/SiO2-I, Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) copreci...

A new, simple, inexpensive, and sensitive method for the simultaneous spectrophotometric determination of Cu(II) and Pd(II) by H-point standard addition method and derivative spectrophotometry is described. 4Phenylpiperazinecarbodithioate (PPDTC) in an anionic micellar solution of SLS was used as a reagent at pH 4. The experimental parameters, such as pH, type of surfactant, concentration of re...

The nanocrystallization processes in Fe-Si-B-Nb-Cu and Fe-Nd-B(-Cu-Nb) amorphous alloys have been studied by transmission electron microscopy (TEM) and a three dimensional atom probe (3DAP). Cu additions are effective in refining the nanocrystalline microstructures of an Fe74.5Si13.5B8Nb3Cu1 alloy and an Fe3B/Nd2Fe14B nanocomposite microstructure. This is because Cu atoms form a high density of...

In this paper, we predict the current-voltage (I-V) characteristics and contact resistance of “end-contacted” metal electrode-graphene and metal electrode-carbon nanotube (CNT) interfaces for five metals, Ti, Pd, Pt, Cu, and Au, based on the first-principles quantum mechanical (QM) density functional and matrix Green’s function methods. We find that the contact resistance (normalized to surface...

Due to unique applications of palladium nanoparticles, synthesis of these nanoparticles by a simple and low cost method is very important. In this work, Pd nanoparticles were synthesized with narrow size distribution by loading metal salt (Pd(OAc)2 ) into the polymeric matrix (PEG) as reducing agent and stabilizer. Also, the effect of metal salt concentration and PEG molecular weight on the con...

To compare the efficacy of L-DOPA administered intranasally in the form of nanoparticles (nano-DOPA) and in standard drug forms using a rat Parkinson's Disease (PD) model. L-DOPA-containing nanoparticles (250±50 nm) were synthesized using the double emulsion method. The efficacy of nano-DOPA therapy was studied in Wistar rats with 6-OHDA-induced PD. Drugs were administered daily, 0.35 mg/kg (by...

By putting a Kondo system of limited dimension inside an insulating matrix, the Kondo screening cloud is confined by the size of the system. This allows us to distinguish the bulk and nano-particle behaviors of such system. We have investigated the magnetic properties of 0.3 at. % Fe-doped Cu clusters with dimensions less than 20 nm embedded in a SiO 2 matrix. The magnetic measurements are cons...

In recent years, metal nano particles such as silver, copper and zinc have developed in textilefinishing. Copper nano particles are used in wound dressings and socks to give them antibacterialproperties. In the present paper, cotton fabrics were treated with different concentrations of Cu nanoparticles colloidal solution. For investigation of the durability of nano particles on cotton fabric,la...

We use first-principles methods to investigate the adsorption of Cu, Pb, Ag, and Mg onto a H-terminated Si surface. We show that Cu and Pb can adsorb strongly while Ag and Mg are fairly inert. In addition, adsorption states of two types are seen to exist for Pb. We also study the clustering energetics of Cu and Pb on the surface and find that while Cu clusters eagerly, Pb may prefer to form onl...